114837-50-2

• 

• Basic information

  1. Product Name: 1-(2-broMophenyl)prop-2-en-1-ol
  2. Synonyms: 1-(2-broMophenyl)prop-2-en-1-ol
  3. CAS NO:114837-50-2
  4. Molecular Formula: C₉H₉BrO
  5. Molecular Weight: 213
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 114837-50-2.mol
  9. Article Data: 19

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: N/A
  3. Flash Point: N/A
  4. Appearance: /
  5. Density: N/A
  6. Refractive Index: N/A
  7. Storage Temp.: N/A
  8. Solubility: N/A
  9. CAS DataBase Reference: 1-(2-broMophenyl)prop-2-en-1-ol(CAS DataBase Reference)
  10. NIST Chemistry Reference: 1-(2-broMophenyl)prop-2-en-1-ol(114837-50-2)
  11. EPA Substance Registry System: 1-(2-broMophenyl)prop-2-en-1-ol(114837-50-2)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 114837-50-2(Hazardous Substances Data)

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• Benzenemethanol, 2-bromo-a-ethenyl-

  Cas No: 114837-50-2

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114837-50-2 Usage

General Description

1-(2-bromophenyl)prop-2-en-1-ol is a chemical compound with the molecular formula C9H9BrO. It is an organic compound that contains a bromine atom, a phenyl group, and a hydroxyl group attached to a propene chain. 1-(2-broMophenyl)prop-2-en-1-ol is commonly used in organic synthesis and pharmaceutical research. It may also have potential applications in the development of new drugs or in the production of specialty chemicals. Additionally, 1-(2-bromophenyl)prop-2-en-1-ol may have uses in the field of materials science and as a chemical intermediate in the manufacturing of various products. Overall, this compound has a variety of potential applications due to its unique chemical structure and properties.

Check Digit Verification of cas no

The CAS Registry Mumber 114837-50-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,8,3 and 7 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 114837-50:
(8*1)+(7*1)+(6*4)+(5*8)+(4*3)+(3*7)+(2*5)+(1*0)=122
122 % 10 = 2
So 114837-50-2 is a valid CAS Registry Number.

114837-50-2Upstream product

• 107-02-8 acrolein 
• 583-53-9 2,3-dibromobenzene 
• 3536-96-7 vinylmagnesium chloride 
• 6630-33-7 ortho-bromobenzaldehyde 
• 1730-25-2 allylmagnesium bromide 
• 1826-67-1 vinyl magnesium bromide 
• 593-60-2 Vinyl bromide 

114837-50-2Downstream Products

• 952149-27-8 3-vinylbenzo[c][1,2]oxaborol-1(3H)-ol 
• 1266481-24-6 1-(2-(5-chloro-4-(5-cyclopropyl-1H-pyrazol-3-ylamino)pyrimidin-2-yl)phenyl)prop-2-en-1-ol 
• 1266481-25-7 1-(2-(4-(4-bromo-5-cyclopropyl-1H-pyrazol-3-ylamino)-5-chloropyrimidin-2-yl)phenyl)prop-2-en-1-ol 
• 1266481-26-8 1-(4-bromo-3-(5-chloro-2-(2-(1-hydroxyallyl)phenyl)pyrimidin-4-ylamino)-5-cyclopropyl-1H-pyrazol-1-yl)ethanone 
• 1375475-07-2 (S)-N-(1-(2-bromophenyl)allyl)benzamide 
• 1213536-21-0 C₉H₁₀BrN 
• 24314-51-0 (+/-)-meloscine 
• 1354722-07-8 1-azido-3-(2-bromophenyl)-6-(triisopropylsilyloxy)hex-4-yn-3-yl methyl carbonate 
• 1370701-16-8 2-((E)-3-(2-bromophenyl)-3-hydroxyprop-1-enyl)benzaldehyde 
• 1370701-03-3 (E)-1-(2-bromophenyl)-3-(3,4-dimethoxyphenyl)prop-2-en-1-ol 

114837-50-2Relevant articles and documents

Synthesis of C5-allylindoles through an iridium-catalyzed asymmetric allylic substitution/oxidation reaction sequence of N-alkyl indolines

Lu, Jiamin,Xu, Ruigang,Zeng, Haixia,Zhong, Guofu,Wang, Meifang,Ni, Zhigang,Zeng, Xiaofei

supporting information, p. 3426 - 3431 (2021/05/07)

Iridium/Br?nsted acid cooperative catalyzed asymmetric allylic substitution reactions at the C5 position of indolines have been reported for the first time. The highly efficient protocol allows rapid access to various C5-allylated products in good to high

[Pd]-Catalyzedpara-selective allylation of phenols: access to 4-[(E)-3-aryl/alkylprop-2-enyl]phenols

Chinnabattigalla, Sreenivasulu,Choudhury, Aditya,Gedu, Satyanarayana

supporting information, p. 8259 - 8263 (2021/10/12)

4-[(E)-3-Arylprop-2-enyl]phenols are omnipresent scaffolds and constitute natural products and biologically significant compounds. Obtusastyrene and obtustyrene are two such phenolic-based natural products isolated fromDalbergia retusa. The development of strategies based on a site-selective allylation, particularly protecting group-free substrates and non-activated coupling agents, is indispensable in organic synthesis. Herein, we present a highly regioselective [Pd]-catalyzedpara-allylation of phenols using simple, inactivated allylic alcohols as allylating coupling partners. Notably, this strategy is successful in open-air and under mild reaction conditions. Besides, the efficacy of the present protocol was demonstrated by the direct synthesis of obtusastyrene and obtustyrene.

Size-Exclusion Borane-Catalyzed Domino 1,3-Allylic/Reductive Ireland–Claisen Rearrangements: Impact of the Electronic and Structural Parameters on the 1,3-Allylic Shift Aptitude

Fegyverneki, Dániel,Kolozsvári, Natália,Molnár, Dániel,Egyed, Orsolya,Holczbauer, Tamás,Soós, Tibor

supporting information, p. 2179 - 2183 (2019/01/04)

The reductive Ireland–Claisen rearrangement through borane-mediated hydrosilylation is reported. The method employs a borane catalyst with a special structural design and affords access to synthetically relevant products with high diastereoselectivity. Depending on electronic and structural parameters, the reaction can be coupled with a 1,3-allylic shift, thus the valence isomer of the Ireland–Claisen product is formed.

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