124649-26-9 Usage
Description
(+)-Tuberonic acid is an organic compound that exhibits tuber-inducing properties and is an analogue of Jasmonic Acid, a key component of the essential oil found in Jasmine. It is known for its ability to stimulate the growth of tubers in plants and has potential applications in various industries.
Uses
Used in Agriculture:
(+)-Tuberonic acid is used as a plant growth regulator for promoting tuber formation in crops such as potatoes. Its tuber-inducing properties make it a valuable tool for enhancing crop yield and quality.
Used in Fragrance Industry:
(+)-Tuberonic acid is used as a key ingredient in the synthesis of Jasmonic Acid, which is a major constituent of the essential oil of Jasmine. It plays a crucial role in the fragrance industry, contributing to the production of various perfumes, scented products, and aromatherapy oils.
Check Digit Verification of cas no
The CAS Registry Mumber 124649-26-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,4,6,4 and 9 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 124649-26:
(8*1)+(7*2)+(6*4)+(5*6)+(4*4)+(3*9)+(2*2)+(1*6)=129
129 % 10 = 9
So 124649-26-9 is a valid CAS Registry Number.
InChI:InChI=1/C12H18O4/c13-7-3-1-2-4-10-9(8-12(15)16)5-6-11(10)14/h1-2,9-10,13H,3-8H2,(H,15,16)/b2-1-/t9-,10+/m1/s1
124649-26-9Relevant articles and documents
First total synthesis of tuberonic acid
Nonaka, Hisato,Wang, Yong-Gang,Kobayashi, Yuichi
, p. 1745 - 1748 (2007)
A vinyl group as an acetic acid side chain was attached to the optically active monoacetate of 4-cyclopentene-1,3-diol with CH2{double bond, long}CHMgBr, LiCl, and a CuCN catalyst to produce the SN2-type product, from which the full carbon skeleton of tuberonic acid was constructed through Mitsunobu inversion, Claisen rearrangement, and Wittig reaction. At the last stage, the THP protective group was removed with MgBr2 in Et2O. The diastereomeric ratio of tuberonic acid and the trans isomer was 92:8 by 1H NMR spectroscopy.
Synthesis of Jasmine Ketolactone
Kitahara,Takeshi,Iwamoto, Minoru,Takagi, Yoshikazu,Mori, Kenji,Matsui, Masanao
, p. 1731 - 1734 (2007/10/02)
The synthesis of jasmine ketolactone 3, a minor component of Italian jasmine oil, via the intramolecular Michael reaction is described.