13706-89-3Relevant articles and documents
Synthesis of α-diones and α-diimines by regioselective α-alkylation of 2,3-alkanediimines
De Kimpe,D'Hondt,Stanoeva
, p. 3879 - 3882 (1991)
While α-diones are not easily alkylated at the α-position via their enolates, the corresponding α-diimines can be alkylated conveniently to afford higher homologues, which are easily hydrolyzed into homologous α-diones.
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Locquin
, p. 1174 (1904)
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Matlin,S.A.,Sammes,P.G.
, p. 2623 - 2630 (1972)
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Rapid microwave-promoted solvent-free oxidation of α-methylene ketones to α-diketones
Lee, Jong Chan,Park, Hong-Jun,Park, Jin Young
, p. 5661 - 5664 (2007/10/03)
A convenient and rapid method for the oxidation of α-methylene ketones to α-diketones has been described involving the reaction of pyridine N-oxide with α-nosyloxy ketone intermediates.
The Autoxidation of Hept-3-yne
Brose, Th.,Pritzkow, W.,Sebald, F.,Voerckel, V.
, p. 951 - 956 (2007/10/02)
In the reaction mixtures of the oxidation of hept-3-yne with molecular oxygen as products of the attack on the C-C triple bond heptane-3,4-dione, propionic and butyric acids and a very small amount of 2-ethylvaleric acid were found.Hept-2-en-4-one and hept-3-en-5-one were probably present, but could not be identified unambiguously.As in the case of the isomeric octynes the main primary reaction products were the hydroperoxides formed by attack on the C-H bonds in α-position to the CC triple bond.