14275-62-8Relevant articles and documents
Wursthorn,Kuivila
, p. 29,38 (1977)
Palladium-catalysed dimerisation-distannylation of arynes: Synthesis and reaction of 2,2′-distannylbiaryls
Yoshida, Hiroto,Tanino, Kenji,Ohshita, Joji,Kunai, Atsutaka
, p. 5678 - 5680 (2007/10/03)
Two molar amounts of arynes were found to insert into a Sn-Sn bond of a distannane in the presence of a sub-stoichiometric amount of a palladium-phosphite complex, affording straight-forwardly 2,2′- distannylbiaryls. The Royal Society of Chemistry 2005.
Carbanions as intermediates in the formation of Grignard reagents
Van Klink, Gerard P.M.,De Boer, Henricus J.R.,Schat, Gerrit,Akkerman, Otto S.,Bickelhaupt, Friedrich,Spek, Anthony L.
, p. 2119 - 2135 (2008/10/08)
The formation of reactive carbanions in Grignard reagents was discussed. Inter- and/or intramolecular migrations of organotin and organosilicon groups were also studied. Results showed that the high percentage of rearrangement reactions proves that the anionic species are not located on a minor pathway.
