146337-49-7Relevant articles and documents
Transition-Metal-Free Silylation of Unactivated C(sp2)-H Bonds withtert-Butyl-Substituted Silyldiazenes
Neil, Baptiste,Lucien, Franck,Fensterbank, Louis,Chauvier, Clément
, p. 13085 - 13090 (2021/11/01)
Aromatic organosilanes bearing C(sp2)-Si bonds have found increasing applications across the chemical science, yet are mostly produced by atom-uneconomical stoichiometric procedures. Catalytic alternatives using hydrosilanes as silicon sources
Selectivity control in gold-catalyzed hydroarylation of alkynes with indoles: Application to unsymmetrical bis(indolyl)methanes
McLean, Euan B.,Cutolo, Francesca M.,Cassidy, Orla J.,Burns, David J.,Lee, Ai-Lan
supporting information, p. 6977 - 6981 (2020/09/12)
Gold-catalyzed hydroarylation of unactivated alkynes with indoles have previously been reported to proceed with double indole addition to produce symmetrical bis(indolyl)methanes (BIMs). We demonstrate for the first time that the selectivity of the gold-c