151797-32-9Relevant articles and documents
2-nitroglycal and efficient synthesis method thereof
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, (2021/08/06)
The invention discloses an efficient synthesis method of 2-nitroglycal, and belongs to the technical field of synthesis of sugar. The structure of the 2-nitroglycal is shown in the specification. Secondly, the invention also provides a preparation method of the 2-nitro saccharide alkene, and the preparation method provided by the invention can be used for efficiently preparing the 2-nitroglycal through one-step synthesis.
Variously substituted glycals are readily prepared from glycosyl bromides using (Cp2TiCl)2
Spencer, Roxanne P.,Schwartz, Jeffrey
, p. 4357 - 4360 (2007/10/03)
Glycosyl halides, variously substituted with ether, acetal, or ester protecting groups, were converted to the corresponding glycals in high yield by reaction with (Cp2TiCl)2. A glycosyl chloride was less reactive than the analogous bromide.