15391-62-5Relevant articles and documents
An unusual thioketal formation: Attempted synthesis of 2,3-dibromo-6,7-benzobicyclo[3.2.1]octa-2, 6-diene
Taskesenligil, Yavuz,Balci, Metin
, p. 7993 - 7998 (1995)
Treatment of 8 with 2 equiv. of NBS gave terra bromide 9 which was converted to the corresponding unsaturated ketone 7. Reaction of 7 with 1,2-ethanedithiol produced the unusual thioketal 14 besides normal ketalization product 13. Reduction of 13 with Raney nickel resulted in the formation of hydrocarbon 17, instead of the expected dibromide 4. Copyright