159878-01-0

• 

• Basic information

  1. Product Name: (R)-Phenylmethyl [3-chloro-2-oxo-1-[(phenylthio)methyl]-propyl]carbamate
  2. Synonyms: (r)-phenylmethyl [3-chloro-2-oxo-1-[(phenylthio)methyl]-propyl]carbamate;(r)-(-)-3-(benzyloxycarbonylamino)-1-chloro-4-phenylthio-2-butanone;Z-D-Phe chloromethyl ketone;(R)-benzyl (4-chloro-3-oxo-1-(phenylthio)butan-2-yl)carbaMate;(R)-Phenylmethyl [3-chloro-2-oxo-1-[(phenylthio)methyl]-propyl]carbamate-4
  3. CAS NO:159878-01-0
  4. Molecular Formula: C₁₈H₁₈ClNO₃S
  5. Molecular Weight: 363.86
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 159878-01-0.mol
  9. Article Data: 10

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 539.871°C at 760 mmHg
  3. Flash Point: 280.304°C
  4. Appearance: /
  5. Density: 1.28
  6. Vapor Pressure: 0mmHg at 25°C
  7. Refractive Index: 1.609
  8. Storage Temp.: N/A
  9. Solubility: N/A
  10. CAS DataBase Reference: (R)-Phenylmethyl [3-chloro-2-oxo-1-[(phenylthio)methyl]-propyl]carbamate(CAS DataBase Reference)
  11. NIST Chemistry Reference: (R)-Phenylmethyl [3-chloro-2-oxo-1-[(phenylthio)methyl]-propyl]carbamate(159878-01-0)
  12. EPA Substance Registry System: (R)-Phenylmethyl [3-chloro-2-oxo-1-[(phenylthio)methyl]-propyl]carbamate(159878-01-0)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 159878-01-0(Hazardous Substances Data)

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• 9,9-SPIROBIFLUORENE

  Cas No: 159878-01-0

• USD $ 3.0-3.0 / Kilogram

• 1 Kilogram

• 1-100 Metric Ton/Month

• Dayang Chem (Hangzhou) Co.,Ltd.
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• Carbamic acid,N-[(1R)-3-chloro-2-oxo-1-[(phenylthio)methyl]propyl]-, phenylmethyl ester

  Cas No: 159878-01-0

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• Hangzhou J&H Chemical Co., Ltd.
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• Carbamic acid,N-[(1R)-3-chloro-2-oxo-1-[(phenylthio)methyl]propyl]-, phenylmethyl ester

  Cas No: 159878-01-0

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• 10 Gram

• 500 Kilogram/Month

• Zibo Hangyu Biotechnology Development Co., Ltd
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• 159878-01-0 C18H18ClNO3S (R)-Phenylmethyl [3-chloro-2-oxo-1-[(phenylthio)methyl]-propyl]carbamate

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• Henan Tianfu Chemical Co., Ltd.
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• (R)-benzyl (4-chloro-3-oxo-1-(phenylthio)butan-2-yl)carbaMate

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• Hangzhou Dingyan Chem Co., Ltd
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• (R)-Phenylmethyl [3-chloro-2-oxo-1-[(phenylthio)methyl]-propyl]carbamate

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• Henan Allgreen Chemical Co.,Ltd
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• Carbamic acid,N-[(1R)-3-chloro-2-oxo-1-[(phenylthio)methyl]propyl]-, phenylmethyl ester

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• (R)-BENZYL [3-CHLORO-2-OXO-1-[(PHENYLTHIO)METHYL]-PROPYL]CARBAMATECAS

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• Hangzhou Fandachem Co.,Ltd
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• benzyl N-[(2R)-4-chloro-3-oxo-1-phenylsulfanylbutan-2-yl]carbamate

  Cas No: 159878-01-0

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• (R)-Phenylmethyl [3-chloro-2-oxo-1-[(phenylthio)methyl]-propyl]carbamate

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159878-01-0 Usage

Uses

(R)-Benzyl (4-chloro-3-oxo-1-(phenylthio)butan-2-yl)carbamate is used in the preparation of HIV protease inhibitor streptolysin, antibacterial Streptococcus.

Check Digit Verification of cas no

The CAS Registry Mumber 159878-01-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,9,8,7 and 8 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 159878-01:
(8*1)+(7*5)+(6*9)+(5*8)+(4*7)+(3*8)+(2*0)+(1*1)=190
190 % 10 = 0
So 159878-01-0 is a valid CAS Registry Number.

InChI:InChI=1/C18H18ClNO3S/c19-11-17(21)16(13-24-15-9-5-2-6-10-15)20-18(22)23-12-14-7-3-1-4-8-14/h1-10,16H,11-13H2,(H,20,22)

159878-01-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name	benzyl N-[(2R)-4-chloro-3-oxo-1-phenylsulfanylbutan-2-yl]carbamate

1.2 Other means of identification

Product number	-
Other names	benzyl diphenylphosphonoacetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:159878-01-0 SDS

159878-01-0Upstream product

• 593-71-5 Chloroiodomethane 
• 197302-33-3 benzyl [(2R)-1-[methoxy(methyl)amino]-1-oxo-3-(phenylsulfanyl)-2-propanyl]carbamate 
• 67-63-0 isopropyl alcohol 
• 82611-65-2 N-benzyloxycarbonyl-S-phenyl-L-cysteine 
• 108-98-5 thiophenol 
• 159878-00-9 ((R)-3-Diazo-2-oxo-1-phenylsulfanylmethyl-propyl)-carbamic acid benzyl ester 
• 26054-60-4 ((S)-2-Oxo-oxetan-3-yl)-carbamic acid benzyl ester 

159878-01-0Downstream Products

• 159878-02-1 benzyl [(2R,3S)-4-chloro-3-hydroxy-1-(phenylsulfanyl)-2-butanyl]carbamate 
• 194086-27-6 benzyl [(2R,3R)-4-chloro-3-hydroxy-1-(phenylsulfanyl)-2-butanyl]carbamate 

159878-01-0Relevant articles and documents

Merging lithium carbenoid homologation and enzymatic reduction: A combinative approach to the HIV-protease inhibitor Nelfinavir

Castoldi, Laura,Ielo, Laura,Hoyos, Pilar,Hernáiz, María J.,De Luca, Laura,Alcántara, Andrés R.,Holzer, Wolfgang,Pace, Vittorio

, p. 2211 - 2217 (2018)

An effective stereocontrolled synthesis of the HIV protease inhibitor Nelfinavir is reported. Two transformations were identified crucial for achieving success: the formation of a densely functionalized α-chloroketone via the homologation of a Weinreb ami

Development of a continuous process for the industrial generation of diazomethane

Proctor, Lee D.,Warr, Antony J.

, p. 884 - 892 (2013/09/06)

The development of a safe process for the industrial generation of diazomethane is described. Diazomethane is produced and consumed in a continuous process capable of generating between 50 and 60 tonnes per year whilst the maximum inventory is maintained

HIV protease inhibitors

-

, (2008/06/13)

HIV protease inhibitors, obtainable by chemical synthesis, inhibit or block the biological activity of the HIV protease enzyme, causing the replication of the HIV virus to terminate. These compounds, as well as pharmaceutical compositions that contain these compounds and optionally other anti-viral agents as active ingredients, are suitable for treating patients or hosts infected with the HIV virus, which is known to cause AIDS.

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