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16165-87-0

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16165-87-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 16165-87-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,1,6 and 5 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 16165-87:
(7*1)+(6*6)+(5*1)+(4*6)+(3*5)+(2*8)+(1*7)=110
110 % 10 = 0
So 16165-87-0 is a valid CAS Registry Number.

16165-87-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name triphenyl(2,2,2-trifluoroethoxy)silane

1.2 Other means of identification

Product number -
Other names (2,2,2-Trifluor-aethoxy)-triphenyl-silan

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16165-87-0 SDS

16165-87-0Downstream Products

16165-87-0Relevant articles and documents

Metal-free hydrogen evolution cross-coupling enabled by synergistic photoredox and polarity reversal catalysis

Cao, Jilei,Lu, Kanghui,Ma, Lishuang,Yang, Xiaona,Zhou, Rong

supporting information, p. 8988 - 8994 (2021/11/23)

A synergistic combination of photoredox and polarity reversal catalysis enabled a hydrogen evolution cross-coupling of silanes with H2O, alcohols, phenols, and silanols, which afforded the corresponding silanols, monosilyl ethers, and disilyl ethers, respectively, in moderate to excellent yields. The dehydrogenative cross-coupling of Si-H and O-H proceeded smoothly with broad substrate scope and good functional group compatibility in the presence of only an organophotocatalyst 4-CzIPN and a thiol HAT catalyst, without the requirement of any metals, external oxidants and proton reductants, which is distinct from the previously reported photocatalytic hydrogen evolution cross-coupling reactions where a proton reduction cocatalyst such as a cobalt complex is generally required. Mechanistically, a silyl cation intermediate is generated to facilitate the cross-coupling reaction, which therefore represents an unprecedented approach for the generation of silyl cationviavisible-light photoredox catalysis.

Spectroscopic investigation of the reactivity of Cp*Ru(PiPr2Ph)X toward H2 and silanes: Formation in solution of Cp*Ru(PiPr2Ph)(H)3 and Cp*Ru(PiPr2Ph)(H)2Y (Y = Halide, OR, and SiR′3)

Johnson, Todd J.,Coan, Paul S.,Caulton, Kenneth G.

, p. 4594 - 4599 (2008/10/08)

Reaction of Cp*RuLX (L = PiPr2Ph; X = Br, I, OSiPh3, NHPh, and OCH2CF3, called ORf) with H2 gives, at -60 °C, Cp*RuLX(H)2, where the two hydride ligands are assigned cisoid positions using 1H NMR spectra. These molecules (except X = Br and I) react with additional H2 to give Cp*RuL(H)3 and liberate HX. Mechanistic possibilities are discussed. Reaction of Cp*RuL(ORf) with HSiR3 (R = Me, Ph, OMe) gives Cp*RuL(H)2SiR3 and (RfO)SiR3. Reaction of Cp*RuL(ORf) with H2SiPh2 gives the two products Cp*RuL(H)2(SiXPh2) (X = H and ORf). Reversible equilibria make these species unstable toward isolation. Mechanistic studies are consistent with the presence of a common intermediate, for which H2SiPh2 and HSi(ORf)Ph2 compete.

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