16725-53-4Relevant articles and documents
SYNTHESIS OF ONE OF THE SEX PHEROMONES OF Heliothis levre - cis-TETRADEC-9-EN-1-OL ACETATE
Dzhumakulov, T.,Yuldashev, A. M.,Abduvakhabov, A. A.
, p. 516 - 517 (1982)
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Polymer-anchored Organosilyl Protecting Group in Organic Synthesis
Chan, Tak-Hang,Huang, Wen-Qiang
, p. 909 - 911 (1985)
Polymer-anchored dimethyl- and diphenyl-chlorosilanes (1a) and (1b) have been prepared and polymer (1b) was found to be useful for the protection of the hydroxy functional group; its use in the synthesis of an insect sex pheromone is reported.
SYNTHESIS OF DEC-5Z-ENYL ACETATE AND TETRADEC-9Z-ENYL ACETATE - COMPONENTS OF THE SEX PHEROMONE OF Agrotis segetum
Verba, G. G.,Bikulova, L. M.,Abduvakhabod, A. A.
, p. 130 - 131 (1988)
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Continuous Flow Z-Stereoselective Olefin Metathesis: Development and Applications in the Synthesis of Pheromones and Macrocyclic Odorant Molecules**
Browne, Duncan L.,Colombel-Rouen, Sophie,Crévisy, Christophe,Curbet, Idriss,Mauduit, Marc,McBride, Tom,Morvan, Jennifer,Roisnel, Thierry
supporting information, p. 19685 - 19690 (2021/08/06)
The first continuous flow Z-selective olefin metathesis process is reported. Key to realizing this process was the adequate choice of stereoselective catalysts combined with the design of an appropriate continuous reactor setup. The designed continuous process permits various self-, cross- and macro-ring-closing-metathesis reactions, delivering products in high selectivity and short residence times. This technique is exemplified by direct application to the preparation of a range of pheromones and macrocyclic odorant molecules and culminates in a telescoped Z-selective cross-metathesis/ Dieckmann cyclisation sequence to access (Z)-Civetone, incorporating a serial array of continually stirred tank reactors.
PRODUCTION OF FATTY OLEFIN DERIVATIVES VIA OLEFIN METATHESIS
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Paragraph 0393, (2017/06/12)
In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.
