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592-41-6 Usage

Definition

ChEBI: An alkene that is hexane carrying a double bond at position 1.

General Description

A clear colorless liquid with a petroleum like odor. Flash point -9°F. Less dense than water and insoluble in water. Vapors heavier than air. Used as a solvent, paint thinner, and chemical reaction medium.

Air & Water Reactions

Highly flammable. Insoluble in water.

Health Hazard

Inhalation may cause giddiness or incoordination similar to that from gasoline vapor. Prolonged exposure to high concentrations may induce loss of consciousness or death.

Reactivity Profile

1--HEXENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.

Purification Methods

Purify it by stirring over Na/K alloy for at least 6hours, then fractionally distil it from sodium under nitrogen. [Beilstein 1 IV 828.]

Uses

Chemical Properties

colourless liquid
InChI:InChI=1/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3

592-41-6 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (52930)  1-Hexene  analytical standard 592-41-6 52930-50ML 3,532.23CNY Detail
Sigma-Aldrich (52930)  1-Hexene  analytical standard 592-41-6 52930-10ML 925.47CNY Detail
Sigma-Aldrich (52930)  1-Hexene  analytical standard 592-41-6 52930-5ML 556.92CNY Detail
Alfa Aesar (B20271)  1-Hexene, 98%    592-41-6 500ml 407.0CNY Detail
Alfa Aesar (B20271)  1-Hexene, 98%    592-41-6 100ml 186.0CNY Detail
Alfa Aesar (B20271)  1-Hexene, 98%    592-41-6 25ml 164.0CNY Detail

592-41-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-hexene

1.2 Other means of identification

Product number -
Other names Dialene 6

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Adhesives and sealant chemicals,Intermediates,Lubricants and lubricant additives,Processing aids, specific to petroleum production,Solvents (which become part of product formulation or mixture),Viscosity adjustors
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:592-41-6 SDS

592-41-6Synthetic route

ethene
74-85-1

ethene

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With trimethylamine-N-oxide; [N(4-C6H4Br)3][B(C6F5)4]; triethylaluminum; [Cr(CO)4(2-C6H4(MeO))2PN(Me)P(2-C6H4(MeO))2] In toluene at 60℃; under 30002.4 Torr; for 1h;100%
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;99%
In chlorobenzene at 60℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;99%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With triphenylphosphine at 200℃; for 6h;100%
With carbon monoxide; C29H32IrN5O; bis(trifluoromethane)sulfonimide lithium In benzene-d6 at 80℃; under 7500.75 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Time; Schlenk technique; chemoselective reaction;98%
With zirconium(IV) chloride; sodium iodide In acetonitrile for 0.0166667h; Heating;88%
1,2-dibromohexane
624-20-4

1,2-dibromohexane

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; ethylmagnesium bromide In tetrahydrofuran at 0℃;100%
With sodium tetrahydroborate; nickel dichloride In tetrahydrofuran at 20℃; for 1h;80%
With tetramethylammonium perchlorate In N,N-dimethyl-formamide Electrolysis;
trimethylstannyl sodium
16643-09-7

trimethylstannyl sodium

6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

(CH3)3Sn((CH2)4CH)

(CH3)3Sn((CH2)4CH)

C

(CH3)3Sn(CH2C5H9)
73017-75-1

(CH3)3Sn(CH2C5H9)

Conditions
ConditionsYield
With tert-butylamine In tetrahydrofuran react. at 0°C under Ar;A 0%
B 100%
C 0%
With DPCH In tetrahydrofuran react. at 0°C under Ar;A <1
B 98%
C 0%
In tetrahydrofuran react. at 0°C under Ar;A 0%
B 98%
C 0%
In tetrahydrofuran; benzene react. at 0°C under Ar;A <1
B 85%
C 10%
With DCPH In tetrahydrofuran; benzene react. at 0°C under Ar;A 15%
B 79%
C 1.5%
hex-1-yne
693-02-7

hex-1-yne

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With hydrogen; N,N′-bis(salicylidene)-ethylenediamino‑palladium In pyridine for 0.35h;98%
With hydrogen In methanol at 20℃; under 760.051 Torr; for 4.5h; Green chemistry;94%
With hydrogen In methanol under 760.051 Torr; for 5.5h;93%
trimethylstannane
1631-73-8

trimethylstannane

6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

lithium diisopropyl amide
4111-54-0

lithium diisopropyl amide

A

1-hexene
592-41-6

1-hexene

B

methyl-cyclopentane
96-37-7

methyl-cyclopentane

C

hexamethyldistannane
661-69-8

hexamethyldistannane

Conditions
ConditionsYield
In diethyl ether; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 2 equiv. of Me3SnH in Et2O at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;A 77%
B 16%
C 97%
In diethyl ether; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 1 equiv. of Me3SnH in Et2O at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;A 41%
B 18%
C 86%
In hexane; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 2 equiv. of Me3SnH in hexane at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;A 76%
B 18%
C 27%
In hexane; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 1 equiv. of Me3SnH in hexane at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;A 45%
B 32%
C 48%
ethene
74-85-1

ethene

A

1-hexene
592-41-6

1-hexene

B

polyethylene

polyethylene

Conditions
ConditionsYield
In chlorobenzene at 60℃; for 4h; Product distribution / selectivity; Autoclave;A 96%
B n/a
In chlorobenzene at 60℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;A 91%
B n/a
methylaluminoxane; tantalum pentachloride In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;A 84%
B n/a
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;A 84%
B n/a
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;A 26%
B n/a
6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

methyl-cyclopentane
96-37-7

methyl-cyclopentane

C

cyclohexane
110-82-7

cyclohexane

Conditions
ConditionsYield
With tris-(trimethylsilyl)silane; 2,2'-azobis(isobutyronitrile) at 70℃;A 4.1%
B 93%
C 2%
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) at 70℃;A 15%
B 83%
C 1.2%
With 9-borabicyclo[3.3.1]nonane dimer; tribenzyltin hydride In toluene at 0℃; Product distribution; variation of reagent;A 29%
B 68%
C 3%
ethene
74-85-1

ethene

A

1-hexene
592-41-6

1-hexene

B

1-Decene
872-05-9

1-Decene

Conditions
ConditionsYield
Cl(1-)*NPr4(1+) at 50℃; under 22502.3 Torr; for 1h;A 91.7%
B 5.5%
modified methylalumoxane; C28H24Cl2FeN2S In n-heptane at 30 - 52℃; under 21446.5 Torr; for 0.5h; Product distribution / selectivity;
With [η5-(3-SiMe3)C5H3CMe2-3,5-Me2C6H3]Ti(TEA) In toluene at 20℃; under 7500.75 Torr; for 0.25h; Pressure; Reagent/catalyst; Temperature; Inert atmosphere;
hex-1-yne
693-02-7

hex-1-yne

A

1-hexene
592-41-6

1-hexene

B

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;A 91%
B n/a
With hydrogen; platinum In ethanol at 30℃; under 15200 Torr; Product distribution; 80 atm;A 41.7%
B 57.3%
With hydrogen; Ni(C17H35COO)2; triethylaluminum In toluene at 40℃; Kinetics; Object of study: selectivity;
ethene
74-85-1

ethene

A

1-hexene
592-41-6

1-hexene

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With CrCl2(tetrahydrofuran)2; N,N'-bis(diphenylphosphino)-N,N'-dimethylpropane-1,3-diamine In methyl cyclohexane at 80℃; under 30003 Torr; for 0.5h; Inert atmosphere;A 9%
B 91%
bis(2-(decylthio)ethyl)amine; chromium chloride In toluene at 90℃; under 33753.4 Torr; for 0.502778 - 0.527778h; Product distribution / selectivity;A 90.85%
B 0.5%
chromium(III)2-ethylhexanoate; trimethylaluminum; N-[bis(2-methoxyphenyl)phosphino]-P,P-bis(2-methoxyphenyl)-N-methylphosphinous amide In methyl cyclohexane; toluene at 60℃; under 36003.6 - 37503.8 Torr; for 0.175h; Product distribution / selectivity;A 89.7%
B 8.5%
ethene
74-85-1

ethene

A

1-butylene
106-98-9

1-butylene

B

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
[Ph2PC6H4C(OB(C6F5)3)O-κ2P,O](η3-CH2CMeCH2) In toluene at 0℃; under 2280.15 Torr; for 1h; Product distribution; Further Variations:; Temperatures; Pressures; oligomerization;A 90%
B 6%
With tetraphenyl phosphonium chloride; chromium at 80℃; under 37503.8 Torr; for 1h; Product distribution / selectivity;A 7.5%
B 88.3%
With [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr2; triethyl aluminum sesquichloride In toluene Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique;A 88%
B 9%
di-n-hexyl diselenide
52056-08-3

di-n-hexyl diselenide

A

1-hexene
592-41-6

1-hexene

B

dodecane
112-40-3

dodecane

Conditions
ConditionsYield
at 600℃; under 20 Torr; for 0.0333333h;A 90%
B 7%
1-(Dichloroamino)-n-hexane
64851-26-9

1-(Dichloroamino)-n-hexane

A

1-hexene
592-41-6

1-hexene

B

hexanenitrile
628-73-9

hexanenitrile

Conditions
ConditionsYield
A 7%
B 88%
2-(but-3-en-1-yl)-2-methyl-1,3-dioxolane
20449-21-2

2-(but-3-en-1-yl)-2-methyl-1,3-dioxolane

5-decene
19689-19-1

5-decene

A

1-hexene
592-41-6

1-hexene

B

2-Methyl-2-((E)-oct-3-enyl)-[1,3]dioxolane

2-Methyl-2-((E)-oct-3-enyl)-[1,3]dioxolane

Conditions
ConditionsYield
aluminum oxide; tetramethylstannane; rhenium(VII) oxide In chlorobenzene at 25℃; for 3h; Yields of byproduct given;A n/a
B 87%
n-hexan-2-ol
626-93-7

n-hexan-2-ol

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With hydrogen bromide; tetrabutyl phosphonium bromide at 200℃; for 0.25h; Menshutkin Reaction; Inert atmosphere;86%
{bis(triphenylphosphine)nitrogen}{cis-HW(CO)4P(OMe)3}
82963-28-8

{bis(triphenylphosphine)nitrogen}{cis-HW(CO)4P(OMe)3}

6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

BrW(CO)4P(OCH3)3(1-)
100504-27-6

BrW(CO)4P(OCH3)3(1-)

Conditions
ConditionsYield
In tetrahydrofuranA 85%
B n/a
1-hexene-3-one
1629-60-3

1-hexene-3-one

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With n-butylsilane; tris(pentafluorophenyl)borate In dichloromethane84%
ethene
74-85-1

ethene

A

homopolymer of ethylene

homopolymer of ethylene

B

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
methylaluminoxane; C33H29Cl3CrNP2 at 24 - 30℃; under 2250.23 - 22502.3 Torr; for 1 - 2h; Product distribution / selectivity;A 3%
B 83%
methylaluminoxane; C23H24Cl3CrNPS at 24 - 30℃; under 22502.3 Torr; for 1h; Product distribution / selectivity;A 18%
B 82%
[CrCl2Me(tetrahydrofuran)3]; C27H26N2; polyamethylaluminoxane-IP; trimethylaluminum In toluene at 50℃; under 7757.43 Torr; for 1h; Product distribution / selectivity;
n-decyl acetate
112-17-4

n-decyl acetate

A

1-hexene
592-41-6

1-hexene

B

1-Decene
872-05-9

1-Decene

D

1-Butyl-2-methylcyclopropane
2511-92-4

1-Butyl-2-methylcyclopropane

E

1-Methyl-2-pentylcyclopropane
41977-37-1

1-Methyl-2-pentylcyclopropane

F

cyclopentene
142-29-0

cyclopentene

Conditions
ConditionsYield
at 495℃; for 0.00727778h; Rate constant; Product distribution; various temp., also in toluene, also with 14C-labelled ester;A 1.03%
B 81.3%
C 1.91%
D 1.2%
E 0.497%
F 0.45%
ethene
74-85-1

ethene

A

homopolymer of ethylene

homopolymer of ethylene

B

1-hexene
592-41-6

1-hexene

C

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
methylaluminoxane; C64H58Cl6Cr2N2O2P4 In dodecane; toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity;A 80%
B n/a
C n/a
methylaluminoxane, aged; C54H54Cl6Cr2N2P4 In dodecane; toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity;A 50%
B n/a
C n/a
methylaluminoxane; C64H58Cl6Cr2N2O2P4 In toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity;A 20%
B n/a
C n/a
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

A

1-hexene
592-41-6

1-hexene

B

formic acid 1-bromomethylpentyl ester
39741-97-4

formic acid 1-bromomethylpentyl ester

Conditions
ConditionsYield
With bromine; triphenylphosphine at 0℃; for 0.583333h;A n/a
B 78%
trimethylstannane
1631-73-8

trimethylstannane

6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

methyl-cyclopentane
96-37-7

methyl-cyclopentane

C

n-butyltrimethyltin
1527-99-7

n-butyltrimethyltin

Conditions
ConditionsYield
With n-butyllithium In octane TMTH (1.00 mmol) and 6-bromo-1-hexene (1.08 mmol) in octane cooled to 0°C under Ar, n-BuLi (1.00 mmol, in octane) added via syringe, stirred for 15 min, quenched with water; analyzed by GC;A 56%
B 30%
C 78%
triethylbenzylammonium ethanolate
95903-96-1

triethylbenzylammonium ethanolate

1-Iodohexane
638-45-9

1-Iodohexane

A

1-hexene
592-41-6

1-hexene

B

ethyl n-hexyl ether
5756-43-4

ethyl n-hexyl ether

Conditions
ConditionsYield
at 20 - 25℃; for 1h; Product distribution; other halogenoalkanes, other alkoxides and alcoholates; var. reaction conditions;A 4.8%
B 75%
at 20 - 25℃; for 1h;A 4.8%
B 75%
1-Iodohexane
638-45-9

1-Iodohexane

A

1-hexene
592-41-6

1-hexene

B

ethyl n-hexyl ether
5756-43-4

ethyl n-hexyl ether

Conditions
ConditionsYield
With triethylbenzylammonium ethanolate at 20 - 25℃; for 1h;A 4.8%
B 75%
1 ,6-dibromohexane
629-03-8

1 ,6-dibromohexane

A

1-hexene
592-41-6

1-hexene

B

hexane
110-54-3

hexane

C

1,5-Hexadien
592-42-7

1,5-Hexadien

D

hexan-1-ol
111-27-3

hexan-1-ol

Conditions
ConditionsYield
With tetramethylammonium perchlorate In 2,2,2-trifluoroethanol; N,N-dimethyl-formamide Electrolysis;A 4%
B 75%
C 5%
D 18%
1 ,6-dibromohexane
629-03-8

1 ,6-dibromohexane

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With magnesium at 600℃;72%
trimethylstannane
1631-73-8

trimethylstannane

6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

methyl-cyclopentane
96-37-7

methyl-cyclopentane

Conditions
ConditionsYield
In diethyl ether Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 2 equiv. of Me3SnH in Et2O under Ar; analyzed by GLPC;A 71%
B 20%
In hexane Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 1 equiv. of Me3SnH in hexane under Ar; analyzed by GLPC;A 51%
B 46%
In diethyl ether Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 1 equiv. of Me3SnH in Et2O under Ar; analyzed by GLPC;A 51%
B 45%
2-trifluoromethylsulfonyloxy-1-hexene
37555-23-0

2-trifluoromethylsulfonyloxy-1-hexene

carbon dioxide
124-38-9

carbon dioxide

A

1-hexene
592-41-6

1-hexene

B

2-butylacrylic acid
4380-88-5

2-butylacrylic acid

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide at 20℃; under 760 Torr; electrolyses, carbon cathode, Mg anode, E=-2.2 V;A 8%
B 70%
With nBuNBF4; bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 20℃; electrochemical reaction;A 8%
B 70%
6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

1,11-dodecadiene
5876-87-9

1,11-dodecadiene

C

methyl-cyclopentane
96-37-7

methyl-cyclopentane

Conditions
ConditionsYield
With potassium In ammonia; tert-butyl alcohol Product distribution; Mechanism; Heating;A 63.6%
B 20.7%
C 0.7%
With potassium In ammonia; tert-butyl alcohol Heating;A 63.6%
B 20.7%
C 0.7%
Dichloromethylsilane
75-54-7

Dichloromethylsilane

1-hexene
592-41-6

1-hexene

n-hexylmethyldichlorosilane
14799-94-1

n-hexylmethyldichlorosilane

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
at 90℃; for 5h; Inert atmosphere;100%
Stage #1: 1-hexene With diethylenetriaminepentaacetic acid (DTPA)-functionalized silica supported Pt at 60℃; for 0.5h;
Stage #2: Dichloromethylsilane at 60℃; for 4h; Catalytic behavior; Temperature; Reagent/catalyst;
99.6%
1-hexene
592-41-6

1-hexene

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With C20H24CoN2O6(1+)*NO3(1-)*H2O; oxygen; isobutyraldehyde In acetonitrile at 60℃; under 760.051 Torr; for 8h; Time; chemoselective reaction;100%
With dihydrogen peroxide; (Bu4N)3K[γ-SiW10O36(PhPO)2] In water at 65℃; for 2h; microwave irradiation;99%
With tert.-butylhydroperoxide In acetonitrile at 65 - 68℃; for 24h;99%
1-hexene
592-41-6

1-hexene

1,2-dibromohexane
624-20-4

1,2-dibromohexane

Conditions
ConditionsYield
With bromine In chloroform at 0℃; for 0.166667h;100%
With bromine In chloroform at 0 - 5℃;93%
With propane 3-bromo-1-(triphenylphosphonium) tribromide In dichloromethane at 20℃; for 0.5h;92%
1-hexene
592-41-6

1-hexene

Hexane-1,2-diol
6920-22-5

Hexane-1,2-diol

Conditions
ConditionsYield
With poly{[CuBa(pyridine-2,5-dicarboxylate)2(H2O)5]*H2O}; dihydrogen peroxide In acetonitrile at 60℃; for 6h; Catalytic behavior; Reagent/catalyst;100%
With N-methyl-2-indolinone; fluorous OsO4 In water; acetone; tert-butyl alcohol at 20℃; for 36h;97%
With N-methyl-2-indolinone; polysulfone microencapsulated OsO4 In water; acetone; acetonitrile at 20℃; for 0.416667h;96%
1-hexene
592-41-6

1-hexene

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; In tetrahydrofuran at 90℃; under 5250.4 Torr; for 0.166667h; Product distribution; other olefins, other catalysts; var. temp., solv., press., and time;100%
With hydrogen; (iPrPDI)Fe(N2)2 at 20℃; under 3040 Torr; for 19h;100%
With Wilkinson's catalyst; hydrogen In dichloromethane-d2 at 45℃; under 3000.3 Torr; for 6h; Concentration; Reagent/catalyst; Solvent; Temperature; Time; Sealed tube; Inert atmosphere;100%
1-hexene
592-41-6

1-hexene

n-hexan-2-one
591-78-6

n-hexan-2-one

Conditions
ConditionsYield
With water; palladium dichloride In N,N-dimethyl-formamide under 1300 Torr; for 5h; Rate constant; Mechanism; oxidation of different olefines by Wacker process; variation of solvent: formamide, tensioactive and cotensioactive component in microemulsions; reaction time;100%
With water; palladium dichloride In various solvent(s) under 1300 Torr; for 0.833333h; closed reactor, in microemulsion with formamide;100%
With Pd(II)(15-crown-5-phen)Cl2; dinitrogen monoxide In N,N-dimethyl acetamide; water at 150℃; under 2250.23 Torr; for 18h;99%
1-hexene
592-41-6

1-hexene

hexyltrichlorosilane
928-65-4

hexyltrichlorosilane

Conditions
ConditionsYield
With trichlorosilane at 90℃; for 5h; Inert atmosphere;100%
With trichlorosilane at 90℃; for 5h; Inert atmosphere;100%
With trichlorosilane; nickel In tetrahydrofuran at 20 - 25℃;94%
1-hexene
592-41-6

1-hexene

2-hexene
592-43-8

2-hexene

Conditions
ConditionsYield
With C10H19B11Cl11PPd In dichloromethane-d2 at 25℃; for 0.0833333h; Inert atmosphere;100%
With aluminum (III) chloride; [(2,6-iPrC6H3NC(Me)C(Me)N-2,6-iPrC6H3)Pd(CH3)(Cl)]; acetonitrile In dichloromethane at 25℃; for 18h; Reagent/catalyst; Darkness; Inert atmosphere;81%
With platinum on activated charcoal; carbon dioxide at 300 - 305℃;
triethylsilane
617-86-7

triethylsilane

1-hexene
592-41-6

1-hexene

n-hexyltriethylsilane
13810-04-3

n-hexyltriethylsilane

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
at 90℃; for 5h; Inert atmosphere;100%
With C26H31F5NZn(1+)*C24BF20(1-) In dichloromethane-d2 at 20℃; for 28h; Reagent/catalyst; Inert atmosphere; Glovebox;100%
1-hexene
592-41-6

1-hexene

dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

dimethylhexylsilyl chloride
3634-59-1

dimethylhexylsilyl chloride

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
With platinum on carbon nanotubes In neat (no solvent) at 20℃; for 24h;97%
dihydrogen hexachloroplatinate In diethyl ether for 15h; Heating;80%
1-hexene
592-41-6

1-hexene

trimethoxysilane
2487-90-3

trimethoxysilane

n-hexyltrimethoxysilane
3069-19-0

n-hexyltrimethoxysilane

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
at 90℃; for 5h; Inert atmosphere;100%
With dichlorobis-(ethylene)-μ,μ'-dichloroplatinum(II)
1-hexene
592-41-6

1-hexene

Triethoxysilane
998-30-1

Triethoxysilane

hexyltriethoxysilane
18166-37-5

hexyltriethoxysilane

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
at 90℃; for 5h; Inert atmosphere;100%
With platinum on carbon nanotubes In neat (no solvent) at 20℃; for 24h;98%
1-hexene
592-41-6

1-hexene

indantrione
938-24-9

indantrione

2-((E)-Hex-2-enyl)-2-hydroxy-indan-1,3-dione
145046-47-5

2-((E)-Hex-2-enyl)-2-hydroxy-indan-1,3-dione

Conditions
ConditionsYield
In chloroform at 80℃; for 4h;100%
1-hexene
592-41-6

1-hexene

triphenylmethylacetonitrile oxide
13412-55-0

triphenylmethylacetonitrile oxide

5-butyl-3-(triphenylmethyl)-2-isoxazoline
123622-72-0

5-butyl-3-(triphenylmethyl)-2-isoxazoline

Conditions
ConditionsYield
In benzene at 85℃; for 48h;100%
1-hexene
592-41-6

1-hexene

sodium 4-methylbenzenesulfinate
824-79-3

sodium 4-methylbenzenesulfinate

2-iodo-1-tosylhexane
71963-96-7

2-iodo-1-tosylhexane

Conditions
ConditionsYield
With iodine In water; ethyl acetate at 20℃; for 1.33333h; iodosulfonization;100%
With iodine In water; ethyl acetate for 2h; Ambient temperature;
1-hexene
592-41-6

1-hexene

α-bromopropionyl 2-oxazolidinone amide
114341-77-4

α-bromopropionyl 2-oxazolidinone amide

4-bromo-2-methyloctanoyl 2-oxazolidinone amide

4-bromo-2-methyloctanoyl 2-oxazolidinone amide

Conditions
ConditionsYield
With triethyl borane; scandium tris(trifluoromethanesulfonate) In hexane; 1,2-dichloro-ethane at 25℃; for 1h;100%
1-hexene
592-41-6

1-hexene

3-bromoacetyl-1,3-oxazolidin-2-one
141353-28-8

3-bromoacetyl-1,3-oxazolidin-2-one

4-bromooctanoyl 2-oxazolidinone amide
224804-26-6

4-bromooctanoyl 2-oxazolidinone amide

Conditions
ConditionsYield
With triethyl borane; ytterbium(III) triflate In hexane; 1,2-dichloro-ethane at 25℃; for 1h;100%
With air; triethyl borane In 2,2,2-trifluoroethanol at 25℃; for 1.5h;90%
With triethyl borane; oxygen; ytterbium(III) triflate In hexane; 1,2-dichloro-ethane at 20℃; for 0.5h;83%
1-hexene
592-41-6

1-hexene

(S)-4-Benzyl-3-((R)-2-bromo-propionyl)-oxazolidin-2-one
114341-80-9

(S)-4-Benzyl-3-((R)-2-bromo-propionyl)-oxazolidin-2-one

4-bromo-2-methyloctanoyl (5(S)-benzyl-2-oxazolidone) amide

4-bromo-2-methyloctanoyl (5(S)-benzyl-2-oxazolidone) amide

Conditions
ConditionsYield
With triethyl borane; scandium tris(trifluoromethanesulfonate) In hexane; 1,2-dichloro-ethane at 25℃; for 1h;100%
1-hexene
592-41-6

1-hexene

9-bora-bicyclo[3.3.1]nonane
280-64-8

9-bora-bicyclo[3.3.1]nonane

9-hexyl-9-borabicyclo[3.3.1]nonane
42371-64-2

9-hexyl-9-borabicyclo[3.3.1]nonane

Conditions
ConditionsYield
In tetrahydrofuran at 60℃; for 12h; Schlenk technique; Inert atmosphere;100%
In tetrahydrofuran at 25℃; for 24h; Schlenk technique; Inert atmosphere;100%
In tetrahydrofuran at 20℃; for 2h;87%
1-hexene
592-41-6

1-hexene

diisobutyl(2,6-di-tert-butyl-4- methylphenoxy)aluminum
56252-56-3

diisobutyl(2,6-di-tert-butyl-4- methylphenoxy)aluminum

C6H13Al(OC6H2(CH3)(C(CH3)3)2(CH2CH(CH3)2))
106751-52-4

C6H13Al(OC6H2(CH3)(C(CH3)3)2(CH2CH(CH3)2))

Conditions
ConditionsYield
With catalyst: ZrCl2(C5H5)2/AlH(CH2CH(CH3)2)2 In xylene react. of the Al compd. with the olefin (mol ratio 1:3) in dry xylene at 140°C for 5-7 h;100%
With catalyst: ZrCl4/AlH(CH2CH(CH3)2)2 In toluene react. of the Al compd. with the olefin (mol ratio 1:3) in toluene for 10 h;78%
With catalyst: (C5H5)2ZrCl2-iBu2AlH In xylene byproducts: isobutene; addn. of Cp2ZrCl2 to phenoxide at 20°C, mixt. stirred 0.5h, addn. of i-Bu2AlH, refluxed and addn. of olefin, reaction time 5 h at 140°C; isobutene condensed in a trap cooled to -78°C;
With catalyst: (C5H5)2ZrCl2-iBu2AlH In toluene byproducts: isobutene; addn. of Cp2ZrCl2 to phenoxide at 20°C, mixt. stirred 0.5h, addn. of i-Bu2AlH, refluxed and addn. of olefin, reaction time 10h at 140°C; isobutene condensed in a trap cooled to -78°C;
With catalyst: ZrCl4/AlH(CH2CH(CH3)2)2 In xylene react. of the Al compd. with the olefin (mol ratio 1:3) in dry xylene at 140°C for 5-7 h;<50
1-hexene
592-41-6

1-hexene

triphenylstannane
892-20-6

triphenylstannane

n-hexyltriphenylstannane
103047-76-3

n-hexyltriphenylstannane

Conditions
ConditionsYield
Irradiation (UV/VIS); UV-irradiation at 25-50 °C for 18 h;;100%
Irradiation (UV/VIS); UV-irradiation at 25-50 °C for 18 h;;100%
1-hexene
592-41-6

1-hexene

[Re(Br)(H)(NO)(PiPr3)2]
1145706-23-5

[Re(Br)(H)(NO)(PiPr3)2]

[Re(Br)(H)(NO)(Pi-Pr3)2(η2-CH2=CHBu)]
1260114-02-0

[Re(Br)(H)(NO)(Pi-Pr3)2(η2-CH2=CHBu)]

Conditions
ConditionsYield
In benzene-d6 (N2, Schlenk) complex and 1-hexane were mixed in C6D6; evapd. in vac. for 24 h; elem. anal.;100%
With BH3*THF or B(C6F5)3 or B(C2H5)3 or B(C6H5)3 (Ar) the complex and boron Lewis acid (B(C6F5)3 or BH3*THF or B(C2H5)3 or B(C6H5)3) were mixed in 1-hexane; detected by NMR spectra;
1-hexene
592-41-6

1-hexene

1,1,1,3,5,5,5-heptamethyltrisiloxan
1873-88-7

1,1,1,3,5,5,5-heptamethyltrisiloxan

3-n-hexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane
1873-90-1

3-n-hexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane

Conditions
ConditionsYield
With 1,3-bis(tert-buthylethynyl)-1,1,3,3-tetramethyldisiloxane platinum (0) at 50℃; for 16h; Time; Reagent/catalyst;100%
With C27H55NOPtSi5 In benzene-d6; toluene at 50℃; for 5h; Reagent/catalyst; Concentration; Schlenk technique; Inert atmosphere;95%
With C24H33N2ORh In tetrahydrofuran at 20℃; for 24h; Time; Inert atmosphere; Glovebox; regioselective reaction;86%
methanol
67-56-1

methanol

1-hexene
592-41-6

1-hexene

2-methoxyhexyltellurium tribromide
1514956-43-4

2-methoxyhexyltellurium tribromide

Conditions
ConditionsYield
With tellurium(IV) tetrabromide for 8h; Heating; regioselective reaction;100%
1-hexene
592-41-6

1-hexene

hydrogen
1333-74-0

hydrogen

hexane
110-54-3

hexane

Conditions
ConditionsYield
With C61H98ClN3P2Ru In dichloromethane-d2 at 50℃; under 3040.2 Torr; for 4h; Reagent/catalyst; Time;100%
With triethylsilane; ReH(NO)2(P(CH(CH3)2)3)2; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave;
With triethylsilane; [ReH(NO)2(P(C6H11)3)2]; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave;
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

1-hexene
592-41-6

1-hexene

1,2-bis(di-tert-butyl)phosphinoethane
4141-59-7

1,2-bis(di-tert-butyl)phosphinoethane

[(dtbpe)Ni(1-hexene)]

[(dtbpe)Ni(1-hexene)]

Conditions
ConditionsYield
In tetrahydrofuran-d8 at 60℃; for 24h; Inert atmosphere;100%

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