195827-82-8Relevant articles and documents
Highly (Z)-Diastereoselective Synthesis of Trifluoromethylated exo-Glycals via Photoredox and Copper Catalysis
Frédéric, Christophe J.-M.,Cornil, Jér?me,Vandamme, Mathilde,Dumitrescu, Lidia,Tikad, Abdellatif,Robiette, Rapha?l,Vincent, Stéphane P.
supporting information, p. 6769 - 6773 (2018/10/24)
Highly (Z)-diastereoselective approaches for the synthesis of trifluoromethylated exo-glycals by copper and photoredox catalysis are described. These complementary reactions are applicable to a wide range of methylene exo-glycals generated from the corresponding pyranoses and furanoses and give trifluoromethylated compounds under mild conditions in moderate to good yields. DFT calculations have allowed a rationalization of the observed (Z)-stereoselectivity.
Synthesis and biological evaluation of truncated α-galactosylceramide derivatives focusing on cytokine induction profile
Toba, Tetsuya,Murata, Kenji,Futamura, Junko,Nakanishi, Kyoko,Takahashi, Bitoku,Takemoto, Naohiro,Tomino, Minako,Nakatsuka, Takashi,Imajo, Seiichi,Goto, Megumi,Yamamura, Takashi,Miyake, Sachiko,Annoura, Hirokazu
experimental part, p. 2850 - 2859 (2012/07/01)
A series of truncated analogs of α-galactosylceramide with altered ceramide moiety was prepared, and evaluated for Th2-biased response in the context of IL-4/IFN-γ ratio. Phytosphingosine-modified analogs including cyclic, aromatic and ethereal compounds
Synthesis of an artificial glycoconjugate polymer carrying P(k)-antigenic trisaccharide and its potent neutralization activity against Shiga-like toxin
Dohi, Hirofumi,Nishida, Yoshihiro,Mizuno, Mitsuharu,Shinkai, Masashige,Kobayashi, Takeshi,Takeda, Tae,Uzawa, Hirotaka,Kobayashi, Kazukiyo
, p. 2053 - 2062 (2007/10/03)
Fluorescence-labeled glycoconjugate polymers carrying carbohydrate segments of a globotriaosyl ceramide (Gb3) were synthesized and subjected to biological assays using Escherichia coli O-157 strains and Shiga-like toxins (Stx-I and Stx-II). For
