100010-91-1Relevant academic research and scientific papers
A FACILE SYNTHESIS OF α,β-DIHYDROXYKETONES VIA TIN(IV) ENEDIOLATES BY UTILIZING THE REDUCING POWER OF BIS(2-PYRIDINETHIOLATO)TIN(II)
Ichikawa, Junji,Mukaiyama, Teruaki
, p. 1009 - 1012 (1985)
Bis(2-pyridenethiolato)tin(II), a stable stannylene, effects oxidative addition to α-dicarbonyl compounds to generate tin(IV) enediolates, which in turn react with aldehydes to give α,β-dihydroxyketones in good yields with moderate diastereoselectivities.
A Facile Synthesis of 2,3-Dihydroxyketones from 1,2-Diketones and Aldehydes Using Samarium Diiodide
Miyoshi, Norikazu,Takeuchi, Seiji,Ohgo, Yoshiaki
, p. 959 - 962 (2007/10/02)
In the presence of samarium diiodide, 1,2-diketones react with aldehydes to afford the corresponding 2,3-dihydroxyketones in good yields with moderate diastereoselectivity.The reaction of unsymmetrical 1,2-diketones with aldehydes gives the products with high regioselectivities.
