1000205-55-9Relevant academic research and scientific papers
Intramolecular oxidative diamination and aminohydroxylation of olefins under metal-free conditions
Kim, Hyun Jin,Cho, Seung Hwan,Chang, Sukbok
, p. 1424 - 1427 (2012/05/20)
A metal-free procedure that is simple to operate and convenient to handle was developed for the facile intramolecular oxidative diamination of olefins using an iodobenzene diacetate oxidant and a halide additive to furnish bisindolines at room temperature. The present reaction is featured by mild conditions, a broad substrate scope, and excellent functional group tolerance. The same protocol was successfully extended to the aminohydroxylation.
Advancing palladium-catalyzed C-N bond formation: Bisindoline construction from successive amide transfer to internal alkenes
Muniz, Kilian
, p. 14542 - 14543 (2008/09/17)
The sequential transfer of two sulfonamides to internal alkenes affords the construction of vicinal diamines. In the presence of a palladium catalyst, the reaction proceeds through two mechanistically different C-N bond formation reactions. It is initiate
