100033-76-9Relevant academic research and scientific papers
SYNTHESIS OF VINYLIC SELENIDES AND TELLURIDES BY THE ADDITION OF ALKANESELENOLATE AND -TELLUROLATE ANIONS TO ACETYLENES
Potapov, Vladimir A.,Amosova, Svetlana V.
, p. 277 - 280 (2007/10/02)
Alkaneselenolate and -tellurolate anions, which are generated from dialkyl dichalcogenides in the system potassium hydroxide-hydrazine hydrate-dimethyl sulfoxide-water, add to acetylene and phenylacetylene to give alkyl vinyl chalcogenides and (Z)-alkyl s
VINYL SELENIDE ANIONS. NEW SYNTHESIS OF VINYL ALKYL SELENIDES
Tiecco, M.,Testaferri, L.,Tingoli, M.,Chianelli, D.,Montanucci, M.
, p. 2225 - 2228 (2007/10/02)
Vinyl selenide anions, generated in DMF at 100 deg C, maintain the configuration of the vinyl methyl selenides from which they are produced by demethylation.This property has been used to effect an efficient three steps one pot stereospecific synthesis of vinyl alkyl selenides from unactivated vinyl halides.
