1000375-90-5Relevant academic research and scientific papers
Allyl deprotection of galacturonic acid derivatives: mechanistic aspects of mercuric-catalyzed prop-1-enyl acetal cleavage
Barbier, Maximilien,Grand, Eric,Kovensky, Jose
, p. 2635 - 2640 (2007)
Different deallylation methods were assayed for selective deprotection of allyl galactopyranosiduronic acid derivatives. A two-step procedure using DABCO and (Ph3P)3RhCl followed by mercuric-assisted cleavage gave quantitative yields. Reaction in the presence of [18O]water allowed us to obtain evidence about the mechanism of prop-1-enyl cleavage.
