methyl (allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosid)uronate

Base Information

• Chemical Name: methyl (allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosid)uronate
• CAS No.: 1000375-90-5
• Molecular Formula: C₃₂H₃₆O₈
• Molecular Weight: 548.633
• Mol file: 1000375-90-5.mol

Synonyms:methyl (allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosid)uronate

Chemical Property of methyl (allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosid)uronate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl (allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosid)uronate

There total 1 articles about methyl (allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosid)uronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosiduronic acid (908601-86-5) + methyl iodide (74-88-4) → methyl (allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosid)uronate (1000375-90-5)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; potassium hydrogencarbonate; In N,N-dimethyl-formamide; at 20 ℃; for 14h;

DOI:10.1016/j.carres.2007.08.019

Reference yield:

methyl (allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosid)uronate (1000375-90-5) → methyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranuronate + methyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-β-D-galactopyranuronate

Guidance literature:

methyl (allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosid)uronate; With 1,4-diaza-bicyclo[2.2.2]octane; Wilkinson's catalyst; In ethanol; water; toluene; for 16h; Heating;

With mercury dichloride; mercury(II) oxide; In water; acetone; at 20 ℃; for 1.5h; Further stages. Title compound not separated from byproducts.;

DOI:10.1016/j.carres.2007.08.019

Reference yield:

methyl (allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosid)uronate (1000375-90-5) → C32H36O9 + methyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-D-galactopyranuronate

Guidance literature:

With sodium acetate; palladium dichloride; In water; acetic acid; for 24h; Title compound not separated from byproducts.;

DOI:10.1016/j.carres.2007.08.019

upstream raw materials:

allyl 2,3-di-O-benzyl-4-O-p-methoxybenzyl-α-D-galactopyranosiduronic acid

methyl iodide