100118-50-1

Basic information

• Product Name: 4-methoxyphenyl-bis(carboxymethylthio)methane
• Synonyms: 4-methoxyphenyl-bis(carboxymethylthio)methane
• CAS NO: 100118-50-1
• Molecular Weight: 302.372
• Mol File: 100118-50-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-methoxyphenyl-bis(carboxymethylthio)methane(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxyphenyl-bis(carboxymethylthio)methane(100118-50-1)
• EPA Substance Registry System: 4-methoxyphenyl-bis(carboxymethylthio)methane(100118-50-1)

Safety Data

• Hazardous Substances Data: 100118-50-1(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 68-11-1 mercaptoacetic acid 

Downstream Products

• 153258-82-3 [Methoxycarbonylmethylsulfanyl-(4-methoxy-phenyl)-methylsulfanyl]-acetic acid methyl ester 

Relevant articles and documents

Solvent-free mechanochemical synthesis of bisthioglycolic acid derivatives: an efficient and versatile strategy for carbon–sulfur bond formation

An eco-friendly, easily achievable and efficient strategy has been explored to synthesize functionalized bisthioglycolic acids using a variety of aldehydes and thioglycolic acid. The employed protocol is solvent free and provides the desirable products in

SYNTHESIS, SPECTRAL STUDIES AND C-S BOND FISSION THROUGH PUMMERER REACTION OF SOME ALKYLDIACETATES

A series of methyl and ethyldiacetates have been synthesized and their structures were identified.Correlation between δ-values of the benzylidene protons and ?-Hammett values has been found.The internal chemical shift Δν of the methylene protons was found to be correlated linearly with ?-Hammett constants indicating that the sulfur atom could transmit a polar effect to the substituent.Studies of H2O2 oxidation suggested that a competition between Pummerer and elimination reactions of the intermediate was involved. Key words: Benzylidene dithio diacetates; (1)HNMR spectra; Pummerer reaction