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1001398-10-2

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1001398-10-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1001398-10-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,0,1,3,9 and 8 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1001398-10:
(9*1)+(8*0)+(7*0)+(6*1)+(5*3)+(4*9)+(3*8)+(2*1)+(1*0)=92
92 % 10 = 2
So 1001398-10-2 is a valid CAS Registry Number.

1001398-10-2Downstream Products

1001398-10-2Relevant academic research and scientific papers

Lipshutz-type bis(amido)argentates for directed: Ortho argentation

Tezuka, Noriyuki,Hirano, Keiichi,Peel, Andrew J.,Wheatley, Andrew E. H.,Miyamoto, Kazunori,Uchiyama, Masanobu

, p. 1855 - 1861 (2020)

Bis(amido)argentate (TMP)2Ag(CN)Li2 (3, TMP-Ag-ate; TMP = 2,2,6,6-tetramethylpiperidido) was designed as a tool for chemoselective aromatic functionalization via unprecedented directed ortho argentation (DoAg). X-Ray crystallographic analysis showed that 3 takes a structure analogous to that of the corresponding Lipshutz cuprate. DoAg with this TMP-Ag-ate afforded multifunctional aromatics in high yields in processes that exhibited high chemoselectivity and compatibility with a wide range of functional groups. These included organometallics- A nd transition metal-susceptible substituents such as methyl ester, aldehyde, vinyl, iodo, (trifluoromethanesulfonyl)oxy and nitro groups. The arylargentates displayed good reactivity with various electrophiles. Chalcogen (S, Se, and Te) installation and azo coupling reactions also proceeded efficiently.

Direct ortho cupration: A new route to regioselectively functionalized aromatics

Usui, Shinya,Hashimoto, Yuichi,Morey, James V.,Wheatley, Andrew E. H.,Uchiyama, Masanobu

, p. 15102 - 15103 (2007)

We have developed a direct regio- and chemoselective method for generating functionalized aromatic cuprate compounds through deprotonative directed ortho cupration using TMP(tetramethylpiperidino)-cuprates (R(TMP)Cu(CN)Li2; R = alkyl, phenyl, o

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