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10025-97-5

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10025-97-5 Usage

Chemical Properties

Brownish-black mass, hygroscopic. Soluble in water, alcohol, and dilute hydrochloric acid.

Uses

Different sources of media describe the Uses of 10025-97-5 differently. You can refer to the following data:
1. Iridium(IV) chloride is used in chemical analysis as testing for nitric acid in the presence of nitrous acid, microscopy and in plating solutions. It acts as a catalyst precursor for the stereoselective reduction of cyclohexanones.
2. Analysis (testing for nitric acid in the presence of nitrous acid), microscopy, plating solution.

Check Digit Verification of cas no

The CAS Registry Mumber 10025-97-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,0,2 and 5 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 10025-97:
(7*1)+(6*0)+(5*0)+(4*2)+(3*5)+(2*9)+(1*7)=55
55 % 10 = 5
So 10025-97-5 is a valid CAS Registry Number.
InChI:InChI=1/4ClH.Ir.H2O/h4*1H;;1H2/q;;;;+4;/p-4/rCl4Ir.H2O/c1-5(2,3)4;/h;1H2

10025-97-5 Well-known Company Product Price

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  • Alfa Aesar

  • (12184)  Iridium(IV) chloride, Premion?, 99.95% (metals basis), Ir 56.5% min   

  • 10025-97-5

  • 0.25g

  • 633.0CNY

  • Detail
  • Alfa Aesar

  • (12184)  Iridium(IV) chloride, Premion?, 99.95% (metals basis), Ir 56.5% min   

  • 10025-97-5

  • 1g

  • 1638.0CNY

  • Detail
  • Alfa Aesar

  • (12184)  Iridium(IV) chloride, Premion?, 99.95% (metals basis), Ir 56.5% min   

  • 10025-97-5

  • 5g

  • 5199.0CNY

  • Detail

10025-97-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Iridium(IV) Chloride, Premion

1.2 Other means of identification

Product number -
Other names Iridium chloride hydrate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10025-97-5 SDS

10025-97-5Synthetic route

chloropentaammineiridium(III) chloride

chloropentaammineiridium(III) chloride

iridium tetrachloride
10025-97-5

iridium tetrachloride

Conditions
ConditionsYield
With HCl with aq. regia;
trinitro triammine iridium(III)

trinitro triammine iridium(III)

A

trichloro triammine iridium(III)
63976-47-6, 60183-09-7, 25456-36-4

trichloro triammine iridium(III)

B

iridium (III) chloride
10025-83-9

iridium (III) chloride

C

iridium tetrachloride
10025-97-5

iridium tetrachloride

Conditions
ConditionsYield
With HCl In not given glowing in sealed tube over 100°C;
iridium tetrachloride monohydrate
92561-82-5, 119401-96-6

iridium tetrachloride monohydrate

iridium tetrachloride
10025-97-5

iridium tetrachloride

Conditions
ConditionsYield
In solid in air; TG and DTA monitoring, X-ray diffraction anal.;
dihydrogen hexachloroiridium(IV) hexahydrate

dihydrogen hexachloroiridium(IV) hexahydrate

iridium tetrachloride
10025-97-5

iridium tetrachloride

Conditions
ConditionsYield
In solid in air; TG and DTA monitoring, X-ray diffraction anal.;
disodium dihydrogen 1,2-diaminopropane-N,N,N',N'-tetraaacetate

disodium dihydrogen 1,2-diaminopropane-N,N,N',N'-tetraaacetate

iridium tetrachloride
10025-97-5

iridium tetrachloride

Na(1+)*Ir(3+)*Cl(1-)*H(1+)*(OOCCH2)2NCH2CH2CH2N(CH2COO)2(4-)*3H2O=Na[IrCl(OOCCH2)2NCH2CH2CH2N(CH2COO)CH2COOH]*3H2O

Na(1+)*Ir(3+)*Cl(1-)*H(1+)*(OOCCH2)2NCH2CH2CH2N(CH2COO)2(4-)*3H2O=Na[IrCl(OOCCH2)2NCH2CH2CH2N(CH2COO)CH2COOH]*3H2O

Conditions
ConditionsYield
In water suspn. of IrCl4 and org. compd. in H2O heated at 150°C for 24 h; filtration, evapn., cooling; elem. anal.;60%
iridium tetrachloride
10025-97-5

iridium tetrachloride

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

{bis(dimethylsulphoxide)protium}{trans-bisdimethylsulphoxidetetrachloroiridate(III)}
103992-30-9, 103992-31-0

{bis(dimethylsulphoxide)protium}{trans-bisdimethylsulphoxidetetrachloroiridate(III)}

Conditions
ConditionsYield
With HCl In dimethyl sulfoxide; isopropyl alcohol IrCl4 reacted with concd. HCl in 2-propanol for 4 h at 55°C, soln. cooled to room temp., DMSO added; soln. was allowed to stand overnight, crystals filtered in air, washed with 2-propanol and ether, dried in vacuo;52%
Li(1+)*(CH3)3C6H2(1-)*(CH3CH2)2O=Li((CH3)3C6H2)*(CH3CH2)2O

Li(1+)*(CH3)3C6H2(1-)*(CH3CH2)2O=Li((CH3)3C6H2)*(CH3CH2)2O

iridium tetrachloride
10025-97-5

iridium tetrachloride

tetramesityliridium

tetramesityliridium

Conditions
ConditionsYield
With SOCl2 In diethyl ether stirred for 1 h; evapn., extn. (light petroleum), filtered, volume reduced, cooled to -30°C;25%
Li(1+)*(CH3)3C6H2(1-)*(CH3CH2)2O=Li((CH3)3C6H2)*(CH3CH2)2O

Li(1+)*(CH3)3C6H2(1-)*(CH3CH2)2O=Li((CH3)3C6H2)*(CH3CH2)2O

iridium tetrachloride
10025-97-5

iridium tetrachloride

trimesityliridium

trimesityliridium

Conditions
ConditionsYield
With SOCl2 In diethyl ether stirred for 1 h, kept at 10°C for 24 h; evapn., extn. (light petroleum), filtered, volume reduced, cooled to -30°C, recrystn. (light petroleum);23%
magnesium oxide
1309-48-4

magnesium oxide

oxygen
80937-33-3

oxygen

iridium tetrachloride
10025-97-5

iridium tetrachloride

Reaxys ID: 11558548

Reaxys ID: 11558548

Conditions
ConditionsYield
Stage #1: magnesium oxide; oxygen; iridium tetrachloride In water at 20 - 120℃; for 2.5h;
Stage #2: at 600℃; for 3h;
iridium tetrachloride
10025-97-5

iridium tetrachloride

iridium

iridium

Conditions
ConditionsYield
With hydrogen sulfide redn.; final treating with NaOH and ethanol;
With V In water deposition of Ir after very long boiling;;
With V In water deposition of Ir after very long boiling;;
quinolinium bromide
32353-67-6

quinolinium bromide

iridium tetrachloride
10025-97-5

iridium tetrachloride

quinolinium iridium(IV) chloride

quinolinium iridium(IV) chloride

Conditions
ConditionsYield
In hydrogenchloride room temp.; washing with cold H2O; drying in air;
dimethylsulfide
75-18-3

dimethylsulfide

iridium tetrachloride
10025-97-5

iridium tetrachloride

dimethyl sulfide; compound with iridium(III)-chloride

dimethyl sulfide; compound with iridium(III)-chloride

Conditions
ConditionsYield
standing during 2 d in sealed vessel; boiling with alc. and acetone;after filtering evapd.;
standing during 2 d in sealed vessel; boiling with alc. and acetone;after filtering evapd.;
dimethylsulfide
75-18-3

dimethylsulfide

iridium tetrachloride
10025-97-5

iridium tetrachloride

trichloro tridimethyl sulfide iridium(III)
35933-29-0

trichloro tridimethyl sulfide iridium(III)

Conditions
ConditionsYield
In ethanol in sealed vessel, heating in water bath 24 h; filtration, evapn. in vac., sol. in hot alc., washing with alc. and ether; recrystn. from warm alc.;
In ethanol in sealed vessel, heating in water bath 24 h; filtration, evapn. in vac., sol. in hot alc., washing with alc. and ether; recrystn. from warm alc.;
Diethyl disulfide
110-81-6

Diethyl disulfide

iridium tetrachloride
10025-97-5

iridium tetrachloride

diethyl disulfide; compound with iridium(II)-chloride

diethyl disulfide; compound with iridium(II)-chloride

Conditions
ConditionsYield
In ethanol by reflux on wather bath; evapn.,(or extd. with alc. the soln. and evapd.), sol. in CHCl3, pptd. with ether;
In ethanol by reflux on wather bath; evapn.,(or extd. with alc. the soln. and evapd.), sol. in CHCl3, pptd. with ether;
(C2H5)(C7H6)N*HBr

(C2H5)(C7H6)N*HBr

iridium tetrachloride
10025-97-5

iridium tetrachloride

benzal ethyl ammonium iridium(IV) chloride

benzal ethyl ammonium iridium(IV) chloride

Conditions
ConditionsYield
In hydrogenchloride room temp.; washing with cold H2O; drying in air;
(CH3)(C7H6)N*HBr

(CH3)(C7H6)N*HBr

iridium tetrachloride
10025-97-5

iridium tetrachloride

benzal methyl ammonium iridium(IV) chloride

benzal methyl ammonium iridium(IV) chloride

Conditions
ConditionsYield
In hydrogenchloride room temp.; washing with cold H2O; drying in air;
2,6-dimethylpyridine hydrobromide
24994-61-4

2,6-dimethylpyridine hydrobromide

iridium tetrachloride
10025-97-5

iridium tetrachloride

lutidinium iridium(IV) chloride

lutidinium iridium(IV) chloride

Conditions
ConditionsYield
In hydrogenchloride room temp.; washing with cold H2O; drying in air;
C6H5(C7H6)NH(1+)*Br(1-)={C6H5(C7H6)NH}Br

C6H5(C7H6)NH(1+)*Br(1-)={C6H5(C7H6)NH}Br

iridium tetrachloride
10025-97-5

iridium tetrachloride

benzal anilinium iridium(IV) chloride

benzal anilinium iridium(IV) chloride

Conditions
ConditionsYield
In hydrogenchloride room temp.; washing with cold H2O; drying in air;
2C8H11N*HBr

2C8H11N*HBr

iridium tetrachloride
10025-97-5

iridium tetrachloride

collidinium iridium(IV) chloride

collidinium iridium(IV) chloride

Conditions
ConditionsYield
In hydrogenchloride room temp.; washing with cold H2O; drying in air;
iso-(C4H9)3N*HBr

iso-(C4H9)3N*HBr

iridium tetrachloride
10025-97-5

iridium tetrachloride

tri-iso-butyl ammonium iridium(IV) chloride

tri-iso-butyl ammonium iridium(IV) chloride

Conditions
ConditionsYield
In hydrogenchloride room temp.; washing with cold H2O; drying in air;
iridium tetrachloride
10025-97-5

iridium tetrachloride

barium carbonate

barium carbonate

iridium(IV) oxide dihydrate

iridium(IV) oxide dihydrate

Conditions
ConditionsYield
In not given by heating the sol. of IrCl4 with BaCO3;
In not given by heating the sol. of IrCl4 with BaCO3;
allylammonium bromide
66934-07-4

allylammonium bromide

iridium tetrachloride
10025-97-5

iridium tetrachloride

allyl ammonium iridium(IV) chloride

allyl ammonium iridium(IV) chloride

Conditions
ConditionsYield
In hydrogenchloride room temp.; washing with cold H2O; drying in air;
isoquinoline hydrobromide
49563-76-0

isoquinoline hydrobromide

iridium tetrachloride
10025-97-5

iridium tetrachloride

iso-quinolinium iridium(IV) chloride

iso-quinolinium iridium(IV) chloride

Conditions
ConditionsYield
In hydrogenchloride room temp.; washing with cold H2O; drying in air;
rubidium bromide

rubidium bromide

iridium tetrachloride
10025-97-5

iridium tetrachloride

rubidium iridium(IV) chloride

rubidium iridium(IV) chloride

Conditions
ConditionsYield
In not given cold satd. RbBr soln.; washing with cold H2O, drying in air;
In not given cold satd. RbBr soln.; washing with cold H2O, drying in air;
rubidium bromide

rubidium bromide

iridium tetrachloride
10025-97-5

iridium tetrachloride

rubidium iridium(IV) bromide

rubidium iridium(IV) bromide

Conditions
ConditionsYield
With hydrogen bromide In not given reactn. of IrCl4 and RbBr; heating of formed prod. with dild. HBr soln.; recrystn. by leading through Br2 vapor;
With HBr In not given reactn. of IrCl4 and RbBr; heating of formed prod. with dild. HBr soln.; recrystn. by leading through Br2 vapor;
caesium bromide

caesium bromide

iridium tetrachloride
10025-97-5

iridium tetrachloride

cesium iridium(IV) bromide

cesium iridium(IV) bromide

Conditions
ConditionsYield
In not given
In not given
caesium bromide

caesium bromide

iridium tetrachloride
10025-97-5

iridium tetrachloride

dicaesium hexachloroiridate(IV)

dicaesium hexachloroiridate(IV)

Conditions
ConditionsYield
In not given room temp.; washing with water, drying on air;
rubidium chloride

rubidium chloride

iridium tetrachloride
10025-97-5

iridium tetrachloride

rubidium iridium(IV) chloride

rubidium iridium(IV) chloride

Conditions
ConditionsYield
In not given at room temp.;
In not given at room temp.;
cesium chloride

cesium chloride

iridium tetrachloride
10025-97-5

iridium tetrachloride

dicaesium hexachloroiridate(IV)

dicaesium hexachloroiridate(IV)

Conditions
ConditionsYield
In not given from hot soln.;
In not given from hot soln.;

10025-97-5Relevant articles and documents

Process for producing p-xylene

-

, (2008/06/13)

In a process for producing p-xylene which comprises catalytically methylating toluene with a methylating agent in the gaseous phase, the improvement wherein (a) said methylation is carried out continuously in a multi-stage reaction system consisting of a plurality of separate series-connected fixed catalyst layers without separating the resulting xylenes in an intermediate stage, (b) said toluene is fed together with hydrogen gas into only the first-stage fixed catalyst layer and passed successively through the subsequent fixed catalyst layers, the amount of toluene fed being such that the total weight hourly space velocity of toluene is from 1 to 300 hr-1, (c) said methylating agent is fed into each of said fixed catalyst layers, if desired together with hydrogen gas, the amount of the methylating agent fed into each catalyst layer being 0.01/t moles to 1/t moles, in which t is the number of methyl groups in the methylating agent, per mole of toluene fed into the first-stage catalyst layer, and the total amount of the methylating agent fed into all of the catalyst layers being within the range of 0.1/t moles to 2/t moles, in which t is as defined, per mole of toluene fed into the first-stage catalyst layer, and (d) each fixed catalyst layer is filled with a catalyst composed of a crystalline aluminosilicate containing magnesium oxide or lanthanide oxide.

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