10025-83-9Relevant articles and documents
Burriel, Ramon,Westrum, Edgar F.,Cordfunke, E. H. P.
, p. 1227 - 1232 (1987)
Cordfunke, E. H. P.
, p. 177 - 185 (1981)
Alfa Aesar
(43380) Iridium(III) chloride, anhydrous, Premion?, 99.99% (metals basis), Ir 63.9% min
10025-83-9
1g
1493.0CNY
Alfa Aesar
(43380) Iridium(III) chloride, anhydrous, Premion?, 99.99% (metals basis), Ir 63.9% min
10025-83-9
5g
5618.0CNY
Alfa Aesar
(12158) Iridium(III) chloride, anhydrous, Ir 62% min
10025-83-9
1g
1124.0CNY
Alfa Aesar
(12158) Iridium(III) chloride, anhydrous, Ir 62% min
10025-83-9
5g
3568.0CNY
Aldrich
(520721) Iridium(III)chloride 99.8% trace metals basis
10025-83-9
520721-1G
3,208.14CNY
Aldrich
(336807) Iridium(III)chloride crystalline
10025-83-9
336807-500MG
1,256.58CNY
Aldrich
(336807) Iridium(III)chloride crystalline
10025-83-9
336807-2G
3,797.82CNY
Version: 1.0
Creation Date: Aug 12, 2017
Revision Date: Aug 12, 2017
Product name | Iridium(III) chloride |
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Product number | - |
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Other names | Iridium trichloride |
Identified uses | For industry use only. |
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Uses advised against | no data available |
Emergency phone number | - |
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Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
More Details:10025-83-9 SDS
iridium (III) chloride
Conditions | Yield |
---|---|
With Cl2 In neat (no solvent) in a flow of Cl2 (free from O2, 1 atm) at 500-620°C; at 600-620°C instantaneous reation; at 445 °C only incomplete reaction even after several hours;; sintering at 650°C; | 100% |
With chlorine | |
With chlorine Irradiation (UV/VIS); reacting with chlorine at 600-620°C by irradn. of sunshine or of magnesium light; |
Conditions | Yield |
---|---|
With chlorine above 600°C, by decompn.; | |
With Cl2 above 600°C, by decompn.; |
Conditions | Yield |
---|---|
at red heat; product is a mixt. of Ir and IrCl3; | |
at red heat; product is a mixt. of Ir and IrCl3; |
A
iridium (III) chloride
B
barium oxalate
Conditions | Yield |
---|---|
In water filtering;evapn.; |
iridium (III) chloride
Conditions | Yield |
---|---|
With Cl2 In neat (no solvent) byproducts: H2O; heating IrCl3*H2O in a flow of chlorine at 450-600 °C, reaction starts even at 310 °C;; | |
at 310°C; |
iridium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride In neat (no solvent) at 440°C; | |
With HCl In neat (no solvent) at 440°C; |
iridium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride In neat (no solvent) at 440°C; | |
With HCl In neat (no solvent) at 440°C; |
iridium (III) chloride
Conditions | Yield |
---|---|
With chlorine by heating; | |
With Cl2 by heating; |
iridium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride at 440 °C; | |
With HCl at 440 °C; |
iridium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride byproducts: AgCl contg. Ir; | |
With HCl byproducts: AgCl contg. Ir; |
iridium (III) chloride
Conditions | Yield |
---|---|
With chlorine In neat (no solvent) in a flow of dry Cl2 at 440°C;; | |
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 600°C; | |
With Cl2 in a flow of dry Cl2 at 550°C, quenching of the product;; | |
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 440°C;; |
iridium (III) chloride
Conditions | Yield |
---|---|
With chlorine In neat (no solvent) in a flow of dry Cl2 at 440°C;; | |
With Cl2 In neat (no solvent) in a flow of dry chlorine at 600°C; | |
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 440°C;; | |
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 550°C, quenching the product;; |
Conditions | Yield |
---|---|
chlorination of iridium powder at about 600°C; |
A
trichloro triammine iridium(III)
B
iridium (III) chloride
C
iridium tetrachloride
Conditions | Yield |
---|---|
With HCl In not given glowing in sealed tube over 100°C; |
B
iridium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride at 440 °C; | |
With HCl at 440 °C; |
iridium (III) chloride
Conditions | Yield |
---|---|
With sulfuric acid concd. H2SO4; | |
With H2SO4 concd. H2SO4; |
iridium hexafluoride
iridium (III) chloride
Conditions | Yield |
---|---|
With dichloromethane In dichloromethane byproducts: CH2ClF, CH2F2, CHClF2; inert atmosphere; excess of CH2Cl2, cooling, warming to room temp.; further byproducts; |
Conditions | Yield |
---|---|
in dry HCl gas flow at 440-500°C; | |
byproducts: Cl2; | |
in dry HCl gas flow at 440-500°C; | |
byproducts: Cl2; |
iridium tetrachloride
iridium (III) chloride
Conditions | Yield |
---|---|
In solid in air; TG and DTA monitoring, X-ray diffraction anal.; |
iridium (III) chloride
Conditions | Yield |
---|---|
In solid Ar atmosphere; TG and DTA monitoring, X-ray diffraction anal.; |
iridium (III) chloride
triphenylphosphine
tris(triphenylphosphine)chloroiridium
Conditions | Yield |
---|---|
In tert-butyl alcohol PPh3 dissolved in hot t-butyl alc., purged with N2, IrCl3 added, refluxed for 72 h under N2; filtered, washed (ether), dried (air); | 94% |
iridium (III) chloride
Conditions | Yield |
---|---|
In water room temp. excess of IrCl3; evapn; dissolving in H2SO4; washing with H2O; heating over 100°C; | 90% |
In water room temp. excess of IrCl3; evapn; dissolving in H2SO4; washing with H2O; heating over 100°C; | 90% |
4-methyl-2-(phenanthren-10-yl)quinoline
iridium (III) chloride
acetylacetone
Ir(4-methyl-2-(phenanthren-10-yl)quinoline(1-))2(acetylacetonate)
Conditions | Yield |
---|---|
With sodium carbonate In 2-methoxy-ethanol; water under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.; | 84% |
iridium (III) chloride
Conditions | Yield |
---|---|
With silver trifluoroacetate In neat (no solvent) 170-195°C, 2-9 h; | 82% |
2-(4-(tert-butyl)phenyl)-4-methylquinoline
iridium (III) chloride
acetylacetone
(2-(4-(tert-butyl)phenyl)-4-methylquinoline)2Ir(acetylacetone)
Conditions | Yield |
---|---|
With sodium carbonate In 2-methoxy-ethanol; water under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.; | 82% |
iridium (III) chloride
(2-mercaptophenyl)diphenylphosphine
Conditions | Yield |
---|---|
With NEt3 In methanol N2-atmosphere; refluxing of IrCl3 with 4 equiv. of ligand and NEt3 (4 h, pptn.); elem. anal.; | 80% |
iridium (III) chloride
dibenzyl methylphosphine
mer-[IrCl3[PMe(CH2Ph)2]3]
Conditions | Yield |
---|---|
In 2-methoxy-ethanol mixt. was refluxed for 3 h; crystals were filtered off, washed with ethanol, dried; elem. anal.; | 77% |
4-methyl-2-(4-(trifluoromethyl)phenyl)-4-methylquinoline
iridium (III) chloride
acetylacetone
Conditions | Yield |
---|---|
With sodium carbonate In 2-methoxy-ethanol; water under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.; | 77% |
2-phenylpyridine
iridium (III) chloride
4,4'-di-tert-butyl-2,2'-bipyridine
Conditions | Yield |
---|---|
In 2-ethoxy-ethanol; water (N2, Schlenk technique); heating iridium compd. and 2 equiv. of triazolederiv. in 2-ethoxyethanol/water (6/1) at 110°C for 19 h, addn. o f bipyridine deriv., stirring at 110°C for 19 h; cooling to room temp., addn. of H2O, washing by Et2O, concg. at 70°C for 10 min, cooling to room temp., addn. of aq. NH4PF6, chromy. (silica gel, CH2Cl2/Me2CO (0-10%)), ppn. with aq. NH4PF6 from CH3OH soln., filtration, washing with H2O, drying; | 76% |
2-heptanone thiosemicarbazone
iridium (III) chloride
Conditions | Yield |
---|---|
In ethanol; water a hot aq. soln. of IrCl3 was mixed with a hot ethanolic soln. of the thiosemicarbazone; refluxing on a water bath for about 2-3 h;; pptn. on cooling; the ppt. was filtered off, washed with 1:1 aq. ethanol, and dried over P4O10; elem. anal.;; | 75% |
Conditions | Yield |
---|---|
With NEt3 In methanol under N2 atm. MeOH soln. IrCl3 and phosphino-thiol in the presence of NEt3 were heated under reflux for 2 h; ppt. was filtered and washed with cold Et2O; elem. anal.; | 75% |
1,1'-thiobis[3-(methylthio)]propane
iridium (III) chloride
{bis(3-methylthiopropyl) sulphide}trichloroiridium(III)
Conditions | Yield |
---|---|
In 2-methoxy-ethanol IrCl3 and ligand were dissolved in 2-methoxyethanol, refluxed with stirring for 1 h; cooled, filtered, solvent was removed in vac., residue was dissolved in CH2Cl2, treated with Et2O; elem. anal.; | 72% |
2-(4-(CF3O)-(C6H4))(5-CF3)pyridine
iridium (III) chloride
Conditions | Yield |
---|---|
With silver trifluoroacetate In neat (no solvent) 170-195°C, 2-9 h; | 72% |
iridium (III) chloride
2,3,8,9‐tetraphenyl‐1,4,7,10‐tetraazacyclododeca‐1,3,7,9‐tetraene
[Ir(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl
Conditions | Yield |
---|---|
In ethanol addn. of hot soln. of metal salt to hot soln. of macrocycle, refluxing (4 h), cooling to room temp., pptn. on volume reduction; filtration, washing (hot EtOH), air drying; elem. anal.; | 72% |
iridium (III) chloride
tris(hexamethyleneiminecarbodithioate)iridium(III)
Conditions | Yield |
---|---|
In methanol; water amixing of solution of IrCl3 in 1:2 H2O/CH3OH with the ligand in H2O under constant stirring; refluxing for 3 h; filtration of ppt.; cwashing with H2O/CH3OH; drying over P2O5 in vacuo; TGA-anal.; x-ray diffraction; elem. anal.; AAS; | 70% |
octan-2-one semicarbazone
iridium (III) chloride
Conditions | Yield |
---|---|
In ethanol; water mixing a hot aq. soln. of IrCl3 with a hot ethanolic soln. of the ligand, refluxing on a water bath for about 2 - 3 h, cooling, pptn.; filtration, washing with aq. ethanol (1:1), drying over P4O10 in vac., elem. anal.; | 70% |
iridium (III) chloride
triphenylphosphine
[Ir(2-(2-naphthyl)-4,6-dimethyl-pyrimidine-H)(PPh3)2Cl2]
Conditions | Yield |
---|---|
In 2-ethoxy-ethanol; water IrCl3 (0.5 mmol), pyrimidine ligand (1.5 mmol), PPh3 (1.5 mmol), 2-ethoxyethanol (15 mml) and H2O (5 ml) refluxed under N2 (12 h); cooled to room temp.; ppt. filtered; washed with H2O and EtOH; chromd. (silica gel column, eluent: CH2Cl2/ethyl acetate (5:1); elem. anal.; | 70% |
4-methyl-2-(naphthalen-1-yl)quinoline
iridium (III) chloride
acetylacetone
Conditions | Yield |
---|---|
With sodium carbonate In 2-methoxy-ethanol; water under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.; | 68% |
iridium (III) chloride
1,2-diamino-benzene
benzil
[Ir(dibenzo[e,k]-2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl
Conditions | Yield |
---|---|
In ethanol mixing hot soln. of metal salt, hot soln. of benzil, addn. of hot soln. of phenylenediamine, refluxing (12 h), volume reduction, cooling to roomtemp. (pptn., 1 d); filtration, washing (hot EtOH), air drying; elem. anal.; | 66% |
2-furyl (m-aminophenylenimine)methyl ketone
iridium (III) chloride
[Ir(2-furyl (m-aminophenylenimine)methyl ketone)Cl3]
Conditions | Yield |
---|---|
In acetone water bath (15 min, pptn.); cooling, filtration, washing (alcohol), drying (owen, 160°C); elem. anal.; | 65% |
N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine
iridium (III) chloride
acetylacetone
Ir(N-(4-(4-methylquinolin-2-yl)-N-phenylbenzenamine(1-))2(acetylacetonate)
Conditions | Yield |
---|---|
With sodium carbonate In 2-methoxy-ethanol; water under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.; | 65% |
iridium (III) chloride
bis(3-methylselenopropyl) selenide
{bis(3-methylselenopropyl) selenide}trichloroiridium(III)
Conditions | Yield |
---|---|
In 2-methoxy-ethanol IrCl3 and ligand were dissolved in 2-methoxyethanol, refluxed with stirring for 1 h; cooled, filtered, solvent was removed in vac., residue was dissolved in CH2Cl2, treated with Et2O; elem. anal.; | 64% |
[2,2]bipyridinyl
4-(1-(2,4-difluorophenyl))-1-benzyl-1,2,3-triazole
iridium (III) chloride
Conditions | Yield |
---|---|
In 2-ethoxy-ethanol; water (N2, Schlenk technique); heating iridium compd. and 2 equiv. of triazolederiv. in 2-ethoxyethanol/water (6/1) at 110°C for 19 h, addn. o f bipyridine, stirring at 110°C for 19 h; cooling to room temp., addn. of H2O, washing by Et2O, concg. at 70°C for 10 min, cooling to room temp., addn. of aq. NH4PF6, chromy. (silica gel, CH2Cl2/Me2CO (0-10%)), ppn. with aq. NH4PF6 from CH3OH soln., filtration, washing with H2O, drying; | 64% |
iridium (III) chloride
Conditions | Yield |
---|---|
With Cl2 In neat (no solvent) in a flow of Cl2 (free from O2, 1 atm) at 500-620°C; at 600-620°C instantaneous reation; at 445 °C only incomplete reaction even after several hours;; sintering at 650°C; | 100% |
With chlorine | |
With chlorine Irradiation (UV/VIS); reacting with chlorine at 600-620°C by irradn. of sunshine or of magnesium light; |
Conditions | Yield |
---|---|
With chlorine above 600°C, by decompn.; | |
With Cl2 above 600°C, by decompn.; |
Conditions | Yield |
---|---|
at red heat; product is a mixt. of Ir and IrCl3; | |
at red heat; product is a mixt. of Ir and IrCl3; |
A
iridium (III) chloride
B
barium oxalate
Conditions | Yield |
---|---|
In water filtering;evapn.; |
iridium (III) chloride
Conditions | Yield |
---|---|
With Cl2 In neat (no solvent) byproducts: H2O; heating IrCl3*H2O in a flow of chlorine at 450-600 °C, reaction starts even at 310 °C;; | |
at 310°C; |
iridium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride In neat (no solvent) at 440°C; | |
With HCl In neat (no solvent) at 440°C; |
iridium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride In neat (no solvent) at 440°C; | |
With HCl In neat (no solvent) at 440°C; |
iridium (III) chloride
Conditions | Yield |
---|---|
With chlorine by heating; | |
With Cl2 by heating; |
iridium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride at 440 °C; | |
With HCl at 440 °C; |
iridium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride byproducts: AgCl contg. Ir; | |
With HCl byproducts: AgCl contg. Ir; |
iridium (III) chloride
Conditions | Yield |
---|---|
With chlorine In neat (no solvent) in a flow of dry Cl2 at 440°C;; | |
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 600°C; | |
With Cl2 in a flow of dry Cl2 at 550°C, quenching of the product;; | |
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 440°C;; |
iridium (III) chloride
Conditions | Yield |
---|---|
With chlorine In neat (no solvent) in a flow of dry Cl2 at 440°C;; | |
With Cl2 In neat (no solvent) in a flow of dry chlorine at 600°C; | |
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 440°C;; | |
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 550°C, quenching the product;; |
Conditions | Yield |
---|---|
chlorination of iridium powder at about 600°C; |
A
trichloro triammine iridium(III)
B
iridium (III) chloride
C
iridium tetrachloride
Conditions | Yield |
---|---|
With HCl In not given glowing in sealed tube over 100°C; |
B
iridium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride at 440 °C; | |
With HCl at 440 °C; |
iridium (III) chloride
Conditions | Yield |
---|---|
With sulfuric acid concd. H2SO4; | |
With H2SO4 concd. H2SO4; |
iridium hexafluoride
iridium (III) chloride
Conditions | Yield |
---|---|
With dichloromethane In dichloromethane byproducts: CH2ClF, CH2F2, CHClF2; inert atmosphere; excess of CH2Cl2, cooling, warming to room temp.; further byproducts; |