10027-06-2

Basic information

• Product Name: norbornan-2-yl prop-2-enoate
• Synonyms: norbornan-2-yl prop-2-enoate;8,9,10-trinorborn-2-yl acrylate;Acrylic acid 2-norbornyl ester;Acrylic acid bicyclo[2.2.1]heptane-2-yl ester;Bicyclo[2.2.1]heptane-2-yl=propenoate
• CAS NO: 10027-06-2
• Molecular Formula: C10H14O2
• Molecular Weight: 154.23
• Mol File: 10027-06-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 237.58°C (rough estimate)
• Flash Point: 81.6°C
• Appearance: /
• Density: 1.0182 (rough estimate)
• Vapor Pressure: 0.12mmHg at 25°C
• Refractive Index: 1.4638 (estimate)
• CAS DataBase Reference: norbornan-2-yl prop-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: norbornan-2-yl prop-2-enoate(10027-06-2)
• EPA Substance Registry System: norbornan-2-yl prop-2-enoate(10027-06-2)

Safety Data

• Hazard Codes: Xn
• Statements: 21-38-43
• Safety Statements: 28
• Hazardous Substances Data: 10027-06-2(Hazardous Substances Data)

Usage

Safety Profile

Moderately toxic by skin contact.Low toxicity by ingestion. When heated to decompositionit emits acrid smoke and irritating vapors.

InChI:InChI=1/C10H14O2/c1-2-10(11)12-9-6-7-3-4-8(9)5-7/h2,7-9H,1,3-6H2

Upstream product

• 498-66-8 norbornene 
• 79-10-7 acrylic acid 
• 498-66-8 norborn-2-ene 
• 34640-76-1 exo-2-norbornyl acetate 
• 497-36-9 Norborneol 
• 292638-85-8 acrylic acid methyl ester 

Relevant articles and documents

Synthesis of Bi- and tricyclic acrylates in the presence of boron trifluoride etherate

The addition of acrylic acid to bicyclo[2.2.1]heptene hydrocarbons and tricyclo[5.2.1.02,6]deca-3,8-diene catalyzed with BF 3·O(C2H5)2 was studied and bi- and tricyclic esters of acrylic acid were syn

Synthesis and transformations of norbornyl acrylates

A simple and more environmentally friendly procedure than that traditionally used was developed for preparation of esters consisting in acrylic acid addition to bicyclo[2.2.1]hept-2-ene and its 5-alkyl derivatives. The acrylates obtained were subjected to hydrogenetion followed by hydrolysis of propionic acid esters. A number of new compounds was obtained; some among them possess a pleasant odor.

Preparation method of (methyl)acrylate with bridged ring structure

The invention relates to a preparation method of (methyl)acrylate with a bridged ring structure. The (methyl)acrylate is synthesized through three-step reaction comprising the following steps: firstly, carrying out direct addition on saturated fatty acid and bridged ring olefin or a derivative thereof; rectifying and purifying, thus removing a byproduct generated by self-polymerization of the bridged ring olefin; then carrying out hydrolysis to obtain corresponding bridged ring alcohol or a derivative thereof; finally, carrying out ester exchange reaction between the (methyl)acrylate and the bridged ring alcohol or the derivative thereof to obtain the (methyl)acrylate with the bridged ring structure. The preparation method provided by the invention is simple, and the steps are easy to operate; a target product is obtained through the three-step reaction and the yield is high; the disadvantages of a rectification process of a direct esterification technology that the requirements are high and the yield is low are overcome; the content of a residual cycloolefin monomer in the product is low; when the preparation method is applied to resin synthesis, the disadvantages that resin becomes yellow and the viscosity is increased can be remarkably relieved.