10027-79-9Relevant academic research and scientific papers
An improved procedure for the conversion of alkenes and glycals to 1,2- diazides using Mn(OAc)3·2H2O in acetonitrile containing trifluoroacetic acid
Snider, Barry B.,Lin, Hong
, p. 1913 - 1922 (1998)
Alkenes and Glycals react with Mn(OAc3)·2H2O and NaN3 in 9:1 acetonitrile-trifluoroacetic acid to give 1,2-diazides in >80% yield. Allylic azides are formed by slow addition of NaN3 to a mixture of alkene, Mn(OA
Influence of the cis/trans configuration on the supramolecular aggregation of aryltriazoles
Tejera, Sara,Caniglia, Giada,Dorta, Rosa L.,Favero, Andrea,González-Platas, Javier,Vázquez, Jesús T.
, p. 2881 - 2888 (2019)
The ability of trans- and cis-1,2-glucopyranosyl and cyclohexyl ditriazoles, synthesized by CuAAC "click" chemistry, to form gels was studied, their physical properties determined, and the self-aggregation behavior investigated by SEM, X-ray, and EDC stud
One-Pot and Stereospecific Synthesis of cis-1,2-Diazides via Mitsunobu Reaction of Epoxides
Goeksu, Sueleyman,Secen, Hasan,Suetbeyaz, Yasar
, p. 2373 - 2378 (2007/10/03)
Mitsunobu reaction of epoxides using hydrazoic acid, diethylazodicarboxylate, and triphenylphosphine as reagents gave the corresponding cis-1,2-diazides in moderate yield. Application of similar reaction conditions to trans-diols furnished the corresponding trans-1,2-diazides.
Hypervalent iodine chemistry: New oxidation reactions using the iodosylbenzene-trimethylsilyl azide reagent combination. Direct α- and β-azido functionalization of triisopropylsilyl enol ethers
Magnus, Philip,Lacour, Jér?me,Evans, P. Andrew,Roe, Michael B.,Huhne, Christopher
, p. 3406 - 3418 (2007/10/03)
Treatment of triisopropylsilyl (TIPS) enol ethers with PhIO/TMSN3/at -18 to -15°C rapidly (5 min) gave β-azido TIPS enol ethers in high yields, with only traces of the α-azido adduct. The reaction is very sensitive to temperature changes, with
New Trialkylsilyl Enol Ether Chemistry: Direct 1,2-Bis-azidonation of Triisopropylsilyl Enol Ethers: an Azido-radical Addition Process Promoted by TEMPO
Magnus, Philip,Roe, Michael B.,Hulme, Christopher
, p. 263 - 266 (2007/10/02)
Treatment of triisopropylsilyl enol ethers with PhIO/TMSN3/TEMPO(cat.) -45 deg C results in 1,2-bis-azidonation, which appears to occur through a radical addition process; the 1-azido group can be replaced by carbon nucleophiles such as allyl,
