100288-67-3Relevant academic research and scientific papers
Serial ligand catalysis: A highly selective allylic C-H oxidation
Chen, Mark S.,Prabagaran, Narayanasamy,Labenz, Nathan A.,White, M. Christina
, p. 6970 - 6971 (2005)
We are reporting a mild, chemo-, and highly regioselective Pd(II)-catalyzed allylic oxidation of α-olefins to furnish branched allylic esters that proceeds via a novel serial ligand catalysis mechanism in which two different ligands (i.e., vinyl sulfoxide 2 and BQ) interact sequentially with the metal to promote distinct steps of the catalytic cycle (i.e., C-H cleavage and π-allyl functionalization, respectively). Copyright
