100398-19-4

Basic information

• Product Name: 4-bromobenzyl 4-bromophenyl sulfide
• Synonyms: 4-bromobenzyl 4-bromophenyl sulfide
• CAS NO: 100398-19-4
• Molecular Formula: C₁₃H₁₀Br₂S
• Molecular Weight: 358.0915
• Mol File: 100398-19-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-bromobenzyl 4-bromophenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-bromobenzyl 4-bromophenyl sulfide(100398-19-4)
• EPA Substance Registry System: 4-bromobenzyl 4-bromophenyl sulfide(100398-19-4)

Safety Data

• Hazardous Substances Data: 100398-19-4(Hazardous Substances Data)

Upstream product

• 13457-82-4 4-bromothiophenol sodium salt 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 100398-15-0 1-bromo-4-(4-bromobenzylsulfinyl)benzene 

Downstream Products

• 100398-15-0 1-bromo-4-(4-bromobenzylsulfinyl)benzene 
• 92060-13-4 4-bromobenzyl 4-bromophenyl sulfone 
• 1427730-47-9 (4-dihydroxyborylphenyl)(4-dihydroxyborylbenzyl)sulfide 

Relevant articles and documents

Mild and efficient deoxygenation of sulfoxides to sulfides with triflic anhydride/potassium iodide reagent system

It was found that the combination of triflic anhydride/potassium iodide was an effective promoter for the deoxygenation of sulfoxides and gave the corresponding sulfides in excellent yield in acetonitrile at room temperature. It is worth mentioning that this reagent system is chemoselective and tolerates various functional groups, such as alkene, ketone, ester, aldehyde, acid, and oxime. Georg Thieme Verlag Stuttgart.

A novel method for the deoxygenation of sulfoxides with the PPh 3/Br2/CuBr system

It was found that the combination of PPh3/Br2/CuBr was an effective promoter for the deoxygenation of sulfoxides and gave the corresponding sulfides in excellent yield in acetonitrile under refluxing conditions. It is worth mentioning that this reagent system is chemoselective, tolerating various functional groups such as carbon-carbon double bond and ketone. Copyright