117360-96-0

Upstream product

• 53293-00-8 hex-5-ynoic acid 
• 78-92-2 iso-butanol 
• 504-02-9 1,3-cylohexanedione 

Downstream Products

• 191278-80-5 3-sec-Butoxy-6-[hydroxy-(2,6,6-trimethyl-cyclohex-1-enyl)-methyl]-cyclohex-2-enone 
• 1108084-86-1 6-allyl-3-sec-butoxy-6-(3,4-dimethoxyphenyl)-cyclohex-2-enone 
• 141090-98-4 3-<3,4-(methylenedioxy)phenyl>-2-cyclohexen-1-ol 
• 20065-80-9 2-(3',4'-dimethoxy-1,2,3,4-tetrahydro-[1,1'-biphenyl]-1-yl)-N,N-imethylacetamide 
• 510-80-5 (3aS^*,7aS^*)-3a-(3,4-dimethoxyphenyl)-1-methyloctahydroindole 
• 20036-55-9 3-<3,4-(dimethoxy)phenyl>-2-cyclohexen-1-ol 
• 20036-53-7 3-<3,4-(dimethoxy)phenyl>-2-cyclohexen-1-one 
• 77545-60-9 5-(2-Cyclohexen-1-on-3-yl)-benzo<1,2-d><1,3>dioxol 
• 67019-55-0 2-(4'-methoxy-1,2,3,4-tetrahydro-[1,1'-biphenyl]-1-yl)-N,N-dimethylacetamide 
• 67019-52-7 2-(4′-methoxy-4-oxo-1,2,3,4-tetrahydro-[1,1′-biphenyl]-1-yl)-N,N-dimethylacetamide 
• 67019-53-8 1-(2-(dimethylamino)ethyl)-4′-methoxy-1,2,3,4-tetrahydro-[1,1′-biphenyl]-4-ol 
• 34603-52-6 1-[2-(dimethylamino)ethyl]-4'-methoxy-2,3-dihydro-[1,1′-biphenyl]-4(1H)-one 
• 34603-53-7 1-[2-(dimethylamino)ethyl]-4'-hydroxy-2,3-dihydro-[1,1'-biphenyl]-4(1H)-one 
• 67019-56-1 4'-methoxy-3,4,5,6-tetrahydro-[1,1'-biphenyl]-3-ol 

Relevant academic research and scientific papers

Concise total syntheses of (±)-mesembrane and (±)-crinane

A straightforward and unified strategy to access Amaryllidaceae alkaloids comprising a cis-3a-aryloctahydroindole scaffold has been developed. The strategy features Eschenmoser-Claisen rearrangement of allylalcohol as a key step for the installation of al

Cyclization of 5-hexynoic acid to 3-alkoxy-2-cyclohexenones

The one-pot cyclization of 5-hexynoic acid to produce 3-alkoxy-2- cyclohexenones proceeds in good yields (58-90%). 3-Hexynoic acid was converted to its acyl chloride with the aid of oxalyl chloride and was cyclized to 3-chloro-2-cyclohexenone upon addition of indium(III) chloride. Subsequent addition of alcohol nucleophiles led to the desired 3-alkoxy-2-cyclohexenones.