117360-96-0

Upstream product

• 53293-00-8 hex-5-ynoic acid 
• 78-92-2 iso-butanol 
• 504-02-9 1,3-cylohexanedione 

Downstream Products

• 13481-16-8 4-methyl-4-(prop-2-enyl)cyclohex-2-en-1-one 
• 117360-99-3 4-methyl-4-(2-propenyl)cyclohexanone 
• 117360-98-2 6-methyl-3-<(1-methylpropyl)oxy>-6-(2-propenyl)-2-cyclohexen-1-one 
• 100414-90-2 4-(3,7-dimethylocta-2,6-dien-1-yl)-3-methylcyclohex-2-en-1-one 
• 100414-94-6 2,6,6-Trimethyl-5-(3,7-dimethylocta-2E,6-dienyl)-1-cyclohexene-1-carboxaldehyde 
• 100414-95-7 3-(3,7-Dimethyl-8-hydroxy-2E,6E-octadienyl)-2,2,6-trimethyl-1-cyclohexene-1-carboxaldehyde 
• 100414-96-8 3-(3,7-Dimethyl-8-oxo-2E,6E-octadienyl)-2,2,6-trimethyl-1-cyclohexene-1-carboxaldehyde 
• 100414-91-3 3,3-Dimethyl-4-(3,7-dimethylocta-2E,6-dienyl)-1-trimethylsilyloxy-1-cyclohexene 
• 100414-92-4 2-(1,1-Dimethoxymethyl)-3,3-dimethyl-4-(3,7-dimethylocta-2E,6-dienyl)-1-cyclohexanone 
• 100414-93-5 2-(1,1-Dimethoxymethyl)-4-(3,7-dimethylocta-2E,6-dienyl)-1,3,3-trimethyl-1-cyclohexanol 
• 1108084-86-1 6-allyl-3-sec-butoxy-6-(3,4-dimethoxyphenyl)-cyclohex-2-enone 
• 141090-98-4 3-<3,4-(methylenedioxy)phenyl>-2-cyclohexen-1-ol 
• 20065-80-9 2-(3',4'-dimethoxy-1,2,3,4-tetrahydro-[1,1'-biphenyl]-1-yl)-N,N-imethylacetamide 
• 510-80-5 (3aS^*,7aS^*)-3a-(3,4-dimethoxyphenyl)-1-methyloctahydroindole 

Relevant academic research and scientific papers

Concise total syntheses of (±)-mesembrane and (±)-crinane

A straightforward and unified strategy to access Amaryllidaceae alkaloids comprising a cis-3a-aryloctahydroindole scaffold has been developed. The strategy features Eschenmoser-Claisen rearrangement of allylalcohol as a key step for the installation of al

Cyclization of 5-hexynoic acid to 3-alkoxy-2-cyclohexenones

The one-pot cyclization of 5-hexynoic acid to produce 3-alkoxy-2- cyclohexenones proceeds in good yields (58-90%). 3-Hexynoic acid was converted to its acyl chloride with the aid of oxalyl chloride and was cyclized to 3-chloro-2-cyclohexenone upon addition of indium(III) chloride. Subsequent addition of alcohol nucleophiles led to the desired 3-alkoxy-2-cyclohexenones.