100429-04-7

Basic information

• Product Name: 3-benzoyl-2,2-dimethyl-5-hydroxy-4-methoxycarbonylthiazolidine
• Synonyms: 3-benzoyl-2,2-dimethyl-5-hydroxy-4-methoxycarbonylthiazolidine
• CAS NO: 100429-04-7
• Molecular Weight: 295.359
• Mol File: 100429-04-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-benzoyl-2,2-dimethyl-5-hydroxy-4-methoxycarbonylthiazolidine(CAS DataBase Reference)
• NIST Chemistry Reference: 3-benzoyl-2,2-dimethyl-5-hydroxy-4-methoxycarbonylthiazolidine(100429-04-7)
• EPA Substance Registry System: 3-benzoyl-2,2-dimethyl-5-hydroxy-4-methoxycarbonylthiazolidine(100429-04-7)

Safety Data

• Hazardous Substances Data: 100429-04-7(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 67089-83-2 3-benzoyl-2,2-dimethyl-4(R)-methoxycarbonylthiazolidine 
• 19907-58-5 4(R)-(methoxycarbonyl)-2,2-dimethylthiazolidine hydrochloride 
• 95095-15-1 2,2-dimethyl-3-benzoyl-4-methoxycarbonylthiazolidine 
• 498-66-8 norborn-2-ene 
• 19907-59-6 methyl (4R)-2,2-dimethylthiazolidine-4-carboxylate 

Downstream Products

• 104654-64-0 3-Benzoyl-2,2-dimethyl-2,3-dihydro-thiazole-4-carboxylic acid methyl ester 
• 67089-89-8 (4R)-3-benzoyl-5t-benzoyloxy-2,2-dimethyl-thiazolidine-4r-carboxylic acid methyl ester 
• 104654-65-1 (4R,5R)-3-Benzoyl-5-chloro-2,2-dimethyl-thiazolidine-4-carboxylic acid methyl ester 

Relevant articles and documents

Cooxidation reaction in the singlet oxygenation of cyclic and benzylic sulifides: S-Hydroperoxysulfonium ylide intermediate as a new epoxidizing species

The reaction of singlet oxygen with a series of 3-benzoyl-4-(methoxycarbonyl)thiazolidine derivatives and alkyl benzyl in methylene chloride in the presence of olefins has been investigated. The reaction of singlet oxygen with the sulfides cooxidation of olefins to the corresponding in substantial yields. The epoxidation of olefins by the active in oxidizing species generated in photosensitized oxygenation of the is provided, that the new epoxidizing is the S-hydroperoxysulfonium ylide intermediate derived from a persulfoxide intermediate by intramolecular α-proton abstraction.

SYNTHESIS AND REACTIONS OF CYCLIC α-HYDROXY SULFIDES

Stable, optically active α-hydroxy sulfides are prepared in high yields by reduction of corresponding α-hydroperoxy sulfides obtained by stereospecific photohydroperoxidation of optically active thiazolidine derivatives.A few reactions as well as spectros