10044-19-6Relevant academic research and scientific papers
Dihydrothiophenes.10. The preparation and Diels-Alder reactions of some sulfur and phosphorus-substituted dienophiles and 2-aza-substituted 1,3-dienes
McIntosh, John M.,Pillon, Lilianna, Z.
, p. 2089 - 2093 (2007/10/02)
The use of 3-carboxylated 2,5-dihydrothiophenes as dienophilic component of the Diels-Alder reaction has been investigated.The yields are generally quite low.The formation of conjugated dienes that are aminated at an interior position of the conjugated chain by formation and thermal decomposition of 3-acetamido-2,5-dihydrothiophenes appears to be a viable route to these useful compounds.One example of the Diels-Alder reaction of 2-carboxylated diethyl vinylphophonates is reported.
