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1004558-41-1

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1004558-41-1 Usage

General Description

Tert-butyl 7-chloro-1H-indole-1-carboxylate is a chemical compound with a molecular formula of C14H15ClNO2. It is a derivative of indole, a heterocyclic organic compound with a bicyclic structure. tert-Butyl 7-chloro-1H-indole-1-carboxylate is commonly used in organic synthesis and pharmaceutical research as it possesses several potential applications due to its unique structure. It is known for its wide range of biological activities and has been studied for its potential use in the development of new drugs and pharmaceuticals. Additionally, it is used as an intermediate in the manufacturing of various organic compounds and can be used as a building block in the synthesis of complex molecules.

Check Digit Verification of cas no

The CAS Registry Mumber 1004558-41-1 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,0,4,5,5 and 8 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1004558-41:
(9*1)+(8*0)+(7*0)+(6*4)+(5*5)+(4*5)+(3*8)+(2*4)+(1*1)=111
111 % 10 = 1
So 1004558-41-1 is a valid CAS Registry Number.

1004558-41-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-BOC 7-Chloroindole

1.2 Other means of identification

Product number -
Other names tert-Butyl 7-chloro-1H-indole-1-carboxylate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1004558-41-1 SDS

1004558-41-1Relevant articles and documents

Stereoselective palladium-catalyzed carboaminoxylations of indoles with arylboronic acids and TEMPO

Kirchberg, Sylvia,Froehlich, Roland,Studer, Armido

, p. 4235 - 4238 (2009)

-

Palladium catalyzed tandem alkenyl- and aryl-C-N bond formation: A cascade N-annulation route to 4-, 5-, 6- and 7-chloroindoles

Henderson, Luke C.,Lindon, Matthew J.,Willis, Michael C.

experimental part, p. 6632 - 6638 (2010/10/03)

A series of trihalogenated alkenylbenzenes undergo consecutive palladium catalyzed inter- and intramolecular amination reactions to deliver a series of 1-functionalized mono-chloroindoles. 4-, 5-, 6- and 7-Chloroindoles can all be prepared; carbamates, anilines and amines can be employed as the N-nucleophile.

Asymmetric Deprotonations: Lithiation of N-(tert-Butoxycarbonyl)indoline with sec-Butyllithium/ (-)-Sparteine

Bertini Gross, Kathleen M.,Jun, Young M.,Beak, Peter

, p. 7679 - 7689 (2007/10/03)

The asymmetric lithiation of N-Boc indoline (1) with s-BuLi/(-)-sparteine and subsequent substitution provides the 2-substituted N-Boc indolines 3 and 5-11 with excellent enantiomeric ratios and in variable yields. The asymmetric lithiation-substitution sequence with N-Boc-7-chloroindoline (12) provides products 13-19 with good enantiomeric ratios. Mechanistic investigation establishes that the enantioselectivities arise from an initial asymmetric deprotonation to provide the enantioenriched and configurationally stable organolithium intermediates (S)-28 and (S)-29, which react stereoselectively with electrophiles.

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