100465-50-7

Basic information

• Product Name: <1,1'-Binaphthalene>-2,2'-diol dibutanoate
• Synonyms: <1,1'-Binaphthalene>-2,2'-diol dibutanoate
• CAS NO: 100465-50-7
• Molecular Weight: 426.512
• Mol File: 100465-50-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: <1,1'-Binaphthalene>-2,2'-diol dibutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: <1,1'-Binaphthalene>-2,2'-diol dibutanoate(100465-50-7)
• EPA Substance Registry System: <1,1'-Binaphthalene>-2,2'-diol dibutanoate(100465-50-7)

Safety Data

• Hazardous Substances Data: 100465-50-7(Hazardous Substances Data)

Upstream product

• 124040-95-5 <1,1'-Binaphthalene>-2,2'-diol butanoate 

Downstream Products

• 25501-32-0 (S)-indanol 
• 18531-99-2 (S)-[1,1']-binaphthalenyl-2,2'-diol 
• 158529-97-6 (R)-1-indanyl butyrate 
• 602-09-5 1,1'-bi-2-naphthol 
• 18531-94-7 (R)-1,1'-Bi-2-naphthol 

Relevant articles and documents

Multiple Enantioselection by an Enzyme-Catalyzed Transacylation Reaction

Multiply enantioselective enzyme-catalyzed transacylation reactions are described.Two instances of triply enantioselective enzyme-catalyzed transacylations are 1) the reaction of rac-1-indanol with rac-1,1'-bi-2-naphthyl-2,2'-dibutyrate to afford (S)-1-indanol, (R)-1-indanylacetate, (S)-1,1'-bi-2-naphthyl-2,2'-diol, and (R)-1,1'-bi-2-naphthyl-2,2'-dibutyrate and 2) the reaction of rac-1-indanol with rac-2,2'-bis(butyroxymethyl)biphenyl to afford (S)-1-indanol, (R)-1-indanylbutyrate, (S)-2,2'-biphenyldimethanol, and (R)-2,2'-bis(butyroxy-methyl)biphenyl.Doubly enantioselective enzyme-catalyzed transacylations are described according to two instances: 1) the reaction of rac-1-indanol with rac-1,1'-bi-2-naphthyl-2-ol-2'-butyrate afforded (S)-1-indanol, (R)-1-indanylacetate, (S)-1,1'-bi-2-naphthyl-2,2'-diol, and (R)-1,1'-bi-2-naphthyl-2-ol-2'-butyrate, and 2) the reaction of rac-1-indanol with 1,3,5-O-methylidne-2,4,6-tri-O-butyrate-myo-inositol to afford (S)-1-indanol, (R)-1-indanylbutyrate, and 1,3,5-O-methylidne-2,6-di-O-butyrate-myo-inositol.Multiply enantioselective enzyme-catalyzed reactions have a merit of the enhancement of enantiomeric excess over singly enantioselective ones. - Key Words Enzyme in organic synthesis; Kinetic resolution; Lipase.