1004987-64-7Relevant academic research and scientific papers
Preparation and X-ray structures of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy(tosyloxy)iodo]benzoic acid: New recyclable hypervalent iodine reagents
Yusubov, Mekhman S.,Funk, Tatyana V.,Chi, Ki-Whan,Cha, Eun-Hye,Ghyung, Hwa Kim,Kirschning, Andreas,Zhdankin, Viktor V.
, p. 295 - 297 (2008)
(Chemical Equation Presented) Preparation, structural characterization, and reactivity of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy-(tosyloxy)iodo]benzoic acid, new recyclable iodine(III) reagents derived from 3-iodosylbenzoic acid, are described. The reduced form of these reagents, 3-iodobenzoic acid, can be easily recovered from the reaction mixtures using ion-exchange resin or basic aqueous workup followed by acidification with HCl.
Development of new recyclable reagents and catalytic systems based on hypervalent iodine compounds
Yusubov, Mekhman S.,Zhdankin, Viktor V.
, p. 185 - 191 (2011/03/19)
Recent advances in the development of polymer-supported iodine(V) oxidants, recyclable monomeric hypervalent iodine(III) reagents and catalytic systems based on hypervalent iodine compounds are discussed. These efficient and environmentally friendly reagents and catalysts are particularly useful for oxidative transformations of alcohols to carbonyl compounds and for oxidations at the benzylic position.
