100556-51-2Relevant articles and documents
Novel highly efficient absolute optical resolution method by serial combination of two asymmetric reactions from acetylene monomers having racemic substituents
Tang, Yanan,Liu, Lijia,Suzuki, Junpei,Teraguchi, Masahiro,Kaneko, Takashi,Aoki, Toshiki
supporting information, p. 450 - 461 (2022/01/15)
For general optical resolution, an optical resolution agent is necessary, and the best agent should be selected for each racemic compound. In this study, we will report that a novel optical resolution method by circularly polarized light (CPL) without any
Organocatalyzed anodic oxidation of aldehydes
Finney, Eric E.,Ogawa, Kelli A.,Boydston, Andrew J.
supporting information; experimental part, p. 12374 - 12377 (2012/09/05)
A method for the catalytic formation of electroauxiliaries and subsequent anodic oxidation has been developed. The process interfaces N-heterocyclic carbene-based organocatalysis with electro-organic synthesis to achieve direct oxidation of catalytically generated electroactive intermediates. We demonstrate the applicability of this method as a one-pot conversion of aldehydes to esters for a broad range of aldehyde and alcohol substrates. Furthermore, the anodic oxidation reactions are very clean, producing only H2 gas as a result of cathodic reduction.
Correlation and prediction of rates of alkaline hydrolysis of some benzoate esters.
Washkuhn,Reutrakul,Robinson
, p. 779 - 781 (2007/10/05)
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