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Tert-butyl alcohol 78-92-2
Cas No: 78-92-2
No Data 1 Kilogram 3000 Metric Ton/Year Hefei TNJ chemical industry co.,ltd Contact Supplier
sec-Butanol Manufacturer/High quality/Best price/In stock
Cas No: 78-92-2
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Hangzhou Dayangchem Co., Ltd. Contact Supplier
Tert-butyl alcohol
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USD $ 1.0-2.0 / Kilogram 1 Kilogram 200 Metric Ton/Month Crovell Biotech (Hebei) Co., Ltd. Contact Supplier
TIANFUCHEM--78-92-2--2-Butanol factory price
Cas No: 78-92-2
USD $ 2000.0-2000.0 / Metric Ton 1 Metric Ton 1000 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier
Factory direct supply 2-Butanol CAS:78-92-2 with best price
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USD $ 7.0-10.0 / Kilogram 1 Kilogram 100 Metric Ton/Month Shandong Zhi Shang Chemical Co.Ltd Contact Supplier
sec-Butanol
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USD $ 1.0-1.5 / Gram 1 Gram 1-100 Metric Ton/Month Baowei Technology Qinhuangdao Co., Ltd Contact Supplier
2-Butanol CAS 78-92-2
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USD $ 1.0-50.0 / Gram 10 Gram 15 Metric Ton/Month HUBEI AOKS TRADE CO.,LTD Contact Supplier
sec-Butanol CAS NO.78-92-2
Cas No: 78-92-2
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2-Butanol with CAS:78-92-2
Cas No: 78-92-2
USD $ 1200.0-1600.0 / Metric Ton 1 Metric Ton 10000 Metric Ton/Month Baoji Guokang Healthchem co.,ltd Contact Supplier
TIANFUCHEM--78-92-2--2-Butanol factory price CAS NO.78-92-2
Cas No: 78-92-2
USD $ 4.0-4.0 / Kilogram 10 Kilogram 5000 Kilogram/Month Weifang Tansen Yiang international trading co., LTD Contact Supplier

78-92-2 Usage

Reactivity Profile

Attacks plastics. [Handling Chemicals Safely 1980. p. 236]. Acetyl bromide reacts violently with alcohols or water (Merck 11th ed. 1989). Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73 1967; J, Org. Chem. 28:1893 1963]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous-carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969].

Physical and Chemical Properties

2-butanol is also known as 2-butanol, methyl ethyl alcohol, chemical formula is CH3CH2CHOHCH3. Molecular weight is 74.12. It is colorless liquid with a strong aroma of mint, flammable, volatile, with optical activity. The molecule has a chiral carbon atom, can be present in three forms of right-handed body, left-handed body and racemic body, dl-body: the relative density is 0.8063. Melting point is-114.7 ℃. Boiling point is 99.5 ℃, 45.5 ℃ (7.999 × 103Pa). The flash point is 34 ℃. The refractive index is 1.3978. d-body: the relative density is 0.8080. Boiling point is 99.5 ℃. The flash point is 24 ℃. The refractive index is 1.3954. Specific rotation is + 13.9 °. l-body: the relative density is 0.8070. Boiling point is 99.5 ℃. The flash point is 28 ℃. The refractive index is 1.3955. Specific rotation is-13.51 ° (25 ℃). 2-butanol oxidation can generate methyl ethyl ketone and acetic acid. Slightly soluble in water (25 ℃ when 12.5ml/100ml), dissolved in acetone, benzene, miscible with ethanol and ether. This product interacts with water to form an azeotropic mixture, the product content is 68%, the total boiling point is 88.5 ℃. Rat oral is LD506480mg/kg. 2-butanol is the main raw material for producing methyl ethyl ketone, butyl acetate, sec-butyl acetate, and also used as a solvent and extraction agent, the raw materials of plasticizers, processing agents, herbicides, but also for synthesis of spices, flavors, coloring agents, wetting agent, cleaning agents and solvents of many natural resin, linseed oil and castor oil.

Chemical Properties

It is slightly sticky colorless flammable liquid, with a strong odor. Melting point is-114.7 ℃, the boiling point is 99.5 ℃, relative density (d204) is 0.808~0.809, the refractive index (nD25) is 1.3949, a flash point is 23.9 ℃. It is soluble in water, miscible in ethanol and ether.

Air & Water Reactions

Highly flammable. Soluble in water.

Dangerous situations

Prolonged inhalation is toxic, it irritates eye and skin. Flammable, flash point is 406 ℃, there is a greater risk of combustion. The allowable concentration in air of US is 100ppm (305mg/m3).

Incompatibility

Sec-butyl alcohol is incompatible with strong oxidizing agents.

Laboratory method for preparing 2-butanol

1, As raw materials 2-butene reacts with sulfuric acid in concentrated sulfuric acid to produce sulfuric acid butyl ester, sulfuric acid ester is then hydrolyzed to produce 2-butanol, and then distillation purification.
Butanol is prepared from 2-butene as raw material
2, 2-butanone is used as raw material, under the action of a Grignard reagent, to prepare 2-butanol.
3, cis-2-butene is used as raw material, under the action of boron hydrides, to prepare d-or l-body.

General Description

A clear colorless liquid with an alcohol odor. Flash point below 0 °F. Less dense than water. Vapors heavier than air. Soluble in water. Moderately irritates the eyes and skin. Prolonged and repeated contact may cause defatting and drying of the skin. Vapors may irritate the nose, throat and respiratory tract. May be harmful by ingestion.

Hazards & Safety Information

Category: Flammable liquid
Toxicity grading: Poisoning
Acute toxicity
Oral-rat LD50: 6480 mg/kg, Intravenous-Mouse LD50: 764 mg/kg
Stimulus data
Eyes-rabbit 100 mg/24 hours    moderate, Skin-rabbit 500 mg/24 hr  mild
Hazardous characteristics
It is explosive when mixed with air, self-oxidized to form explosive peroxides.
Flammability hazard characteristics
in case of fire, high temperature, oxidant, it is flammable, burning to generate irritation smoke, spontaneous combustion in contact with chromium trioxide.
Storage characteristics
Treasury ventilation low-temperature drying, and it is stored from oxidants.
Extinguishing agent
Dry powder, water spray, carbon dioxide, foam
Professional standards
TWA 100 PPM (310 mg/m3)

Purification Methods

Purification methods are the same as for n-Butanol. These include drying with K2CO3 or CaSO4, followed by filtration and fractional distillation, refluxing with CaO, distillation, then refluxing with magnesium and redistillation, and refluxing with, then distilling from CaH2. Calcium carbide has also been used as a drying agent. The anhydrous alcohol is obtained by refluxing with sec-butyl phthalate or succinate. (For method see Ethanol.) Small amounts of alcohol can be purified via conversion to the alkyl hydrogen phthalate and recrystallisation [Hargreaves J Chem Soc 3679 1956]. For purification of optical isomers, see Timmermans and Martin [J Chem Phys 25 411 1928]. [Beilstein 2 III 1566.]

Chemical Properties

Colourless liquid

Storage

It is Stored in metal drums, to prevent mechanical damage, best stored in a cool, dry and ventilated, non-flammable place, away from all possible sources of ignition, separated from strong oxidants.

Definition

ChEBI: A secondary alcohol that is butane substituted by a hydroxy group at position 2.

Butanol isomers

Butanol is an important industrial raw material, also known as hydroxy butane, a monohydric alcohol, the lowest level alcohol for the same family which can have two or more isomers, butanol has four kinds of isomers, namely n-butanol, 2-butanol, tert-butanol and isobutanol. Relative molecular mass is 74.12. Butanol has the common property of alcohols, such as water-like, reacts with metal to produce alkoxide, reacts with halogen acid to produce halogenated hydrocarbons, dehydrates into alkenes, oxidation (or dehydrogenation) reaction to produce aldehydes and acids, and reacts with organic acids or oxygen-containing inorganic acid to generate ester and so on. In the four isomers, the toxicity of n-butanol is minimal, the toxicity of the other three is not large, but their irritation is great, with irritation to the skin and mucous membrane. Inhalation of large vapors can cause coma. The maximum allowable concentration at workplace is 100 × 10-6. Butanol can be directly used as a solvent, extraction agent, dehydrating agent, plasticizer, mineral processing agent, anti-aging agent, herbicide and so on.
Physical and chemical properties and toxicity of butanol are different due to isomers. The solubility in water depends on their structure, chemical properties depend on hydroxy location in alcohol: n-butanol and iso-butanol are primary alcohols, can be oxidized into the corresponding aldehyde or acid, sec-butyl alcohol is oxidized into the corresponding ketone, t-butanol is unsusceptible to oxidation.
Physicochemical properties comparison chart of 4 isomers of butanol
Physicochemical properties comparison chart of 4 isomers of butanol
Under dehydrating catalyst, butanol can produce butene, n-butanol and 2-butene can give 1-butene, 2-butene, 2-butanol can generate 2-butene, isobutanol and tert-butanol generate isobutylene. Under the catalyst of copper and silver, the dehydrogenation generates carbonyl compounds, n-butanol generates butyraldehyde, butanol generates methyl ethyl ketone, isobutanol generate isobutyraldehyde. Under the catalyst, air oxidation can generate acid. Catalyzed by a mineral acid, it reacts with organic acid to generate ester. Reaction with benzene, can generate butyl benzene. Butanol reacts with chlorine to generate butyraldehyde chloride. Under the action of the aluminum catalyst at 300~350 ℃, reacts with ammonia, n-butanol, iso-butanol and 2-butanol react with ammonia to generate butylamine, dibutylamine, tributylamine, t-butanol does not have this character. N-butanol and tert-butanol at 180 ℃ react with hydrogen sulfide to generate butyl mercaptan.
The above information were collated and edited by Xiaonan of Chemicalbook.

Uses

1. Used as extraction solvent, spices.
2. 2-butanol is Used as a solvent, and chromatography reagents
3. 2-butanol is Used for the production of intermediates of methyl ethyl ketone, for the preparation of butyl acetate, sec-butyl, used as plasticizers, processing agents, herbicides, solvents and so on.
4. Used for the production of intermediates of methyl ethyl ketone, for the preparation of butyl acetate, sec-butyl.

Transport requirements

During transportation, "flammable liquid" shall be marked logo on the container. Others should be the same with "n-butanol".

Extinguish measures

When firing, dry powder fire extinguishing agent, fire-resistant foam or CO2 can be used. Water fighting is invalid, but spray with water in the fire container to keep it cool. If spills, and spills are not lighted, water mist can wash spray spills from the fire, and dilute to non-flammable mixtures. If necessary, water mist can be used to protect the operator to stop the leakage. Other items see the "n-butanol."

Production method

After adsorption by butane of the cracking petroleum or natural gas in sulfuric acid, then hydrolyze with steam.
InChI:InChI=1/C4H10O/c1-3-4(2)5/h4-5H,3H2,1-2H3

78-92-2 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (96870)  2-Butanol  analytical standard 78-92-2 96870-10ML-F 2,540.07CNY Detail
Sigma-Aldrich (96870)  2-Butanol  analytical standard 78-92-2 96870-1ML-F 356.85CNY Detail
USP (1081829)  2-Butanol  United States Pharmacopeia (USP) Reference Standard 78-92-2 1081829-3X1.2ML 4,326.66CNY Detail
Sigma-Aldrich (19440)  2-Butanol  puriss. p.a., Reag. Ph. Eur., ≥99.5% (GC) 78-92-2 19440-2.5L 1,698.84CNY Detail
Sigma-Aldrich (19440)  2-Butanol  puriss. p.a., Reag. Ph. Eur., ≥99.5% (GC) 78-92-2 19440-1L 698.49CNY Detail
Sigma-Aldrich (19440)  2-Butanol  puriss. p.a., Reag. Ph. Eur., ≥99.5% (GC) 78-92-2 19440-250ML 303.03CNY Detail
Sigma-Aldrich (PHR1563)  2-Butanol  pharmaceutical secondary standard; traceable to USP 78-92-2 PHR1563-3X1.2ML 791.15CNY Detail
Sigma-Aldrich (B85919)  2-Butanol  ReagentPlus®, ≥99% 78-92-2 B85919-6X1L 380.25CNY Detail
Sigma-Aldrich (B85919)  2-Butanol  ReagentPlus®, ≥99% 78-92-2 B85919-4L 1,618.11CNY Detail
Sigma-Aldrich (B85919)  2-Butanol  ReagentPlus®, ≥99% 78-92-2 B85919-1L 634.14CNY Detail
Sigma-Aldrich (294810)  2-Butanol  anhydrous, 99.5% 78-92-2 294810-1L 1,024.92CNY Detail
Sigma-Aldrich (294810)  2-Butanol  anhydrous, 99.5% 78-92-2 294810-100ML 521.82CNY Detail

78-92-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name butan-2-ol

1.2 Other means of identification

Product number -
Other names 3-Methylthiocrotonic acid,S-sec-butyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

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