100596-91-6Relevant academic research and scientific papers
Cyanation of Allylic Carbonates and Acetates Using Trimethylsilyl Cyanide Catalyzed by Palladium Complex
Tsuji, Yasushi,Yamada, Naoaki,Tanaka, Shinsuke
, p. 16 - 17 (2007/10/02)
Allylic carbonates and acetates are cyanated with trimethylsilyl cyanide in the presence of a catalytic amount (5 mol percent based on the allylic substrates) od Pd(PPh3)4 or Pd(CO)(PPh3)3 in THF under reflux to afford β,γ-unsaturated nitriles in high yields.
Homogeneous Metathesis of Unsaturated Nitriles
Bosma, Ruud H. A.,Kouwenhoven, Arjan P.,Mol, Johannes C.
, p. 1081 - 1082 (2007/10/02)
Unsaturated nitriles of general formula CH2=CHnCN, where 1 = n = 4, undergo metathesis in the presence of the catalyst system tungsten hexachloride-tetramethyltin with maximum reactivity for n = 2.
