100615-32-5Relevant academic research and scientific papers
Synthesis of ureas in the bio-alternative solvent Cyrene
Mistry, Liam,Mapesa, Kopano,Bousfield, Thomas W.,Camp, Jason E.
supporting information, p. 2123 - 2128 (2017/07/24)
Cyrene as a bio-alternative solvent: a highly efficient, waste minimizing protocol for the synthesis of ureas from isocyanates and secondary amines in the bio-available solvent Cyrene is reported. This method eliminated the use of toxic solvents, such as
Combining gold(I)/gold(III) catalysis and C-H functionalization: A formal intramolecular [3+2] annulation towards tricyclic indolines and mechanistic studies
Zhang, Guozhu,Luo, Yingdong,Wang, Yanzhao,Zhang, Liming
supporting information; experimental part, p. 4450 - 4454 (2011/06/22)
Gold rush: A combination of oxidative gold(I)/gold(III) catalysis and C-H functionalization led to the first oxidative coupling between in situ generated alkyl gold reagents and C sp 2-H bonds, affording tricyclic indolines through a formal [3+2] annulation between a vinyl group and an aniline moiety [see scheme; Tf=trifluoromethanesulfonyl, Selectfluor=1-chloromethyl-4-fluoro-1,4- diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)]. Copyright
Iodine(V) reagents in organic synthesis. Part 1. Synthesis of polycyclic heterocycles via Dess-Martin periodinane-mediated cascade cyclization: Generality, scope, and mechanism of the reaction
Nicolaou,Baran,Zhong,Sugita
, p. 2212 - 2220 (2007/10/03)
The scope, generality, and mechanism of the Dess-Martin periodinane-mediated cyclization reaction of unsaturated anilides discovered during the total synthesis of the CP-molecules (phomoidrides A and B) are delineated. A plethora of heterocyclic compounds
