124-02-7

Basic information

• Product Name: N,N-Diallylamine
• Synonyms: 2-propen-1-amine, N-2-propen-1-yl-;N-(prop-2-en-1-yl)prop-2-en-1-amine;N-Allyl-2-propen-1-amine;N-Allylprop-2-en-1-amine;Diallylamine
• CAS NO: 124-02-7
• Molecular Formula: C₆H₁₁N
• Molecular Weight: 97.15824
• EINECS: 204-671-2
• Mol File: 124-02-7.mol
• Article Data: 22

Chemical Properties

• Melting Point: -88℃
• Boiling Point: 115.3 °C at 760 mmHg
• Flash Point: 15.6 °C
• Appearance: clear colourless to yellow liquid
• Density: 0.767 g/cm³
• Vapor Pressure: 19.2mmHg at 25°C
• Refractive Index: 1.432
• PKA: 9.02±0.20(Predicted)
• Water Solubility: 8.6 g/100mL
• CAS DataBase Reference: N,N-Diallylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-Diallylamine(124-02-7)
• EPA Substance Registry System: N,N-Diallylamine(124-02-7)

Safety Data

• Hazard Codes: F:Flammable;;
• Statements: R11:; R20/22:; R24:; R34:
• Safety Statements: S16:; S26:; S28A:; S36/37/39:; S45:
• RIDADR: 2359
• HazardClass: 3
• PackingGroup: II
• Hazardous Substances Data: 124-02-7(Hazardous Substances Data)

Usage

General Description

N,N-Diallylamine is an organic compound with the chemical formula C6H13N. It is a colorless liquid with a strong, ammonia-like odor. N,N-Diallylamine is primarily used as an intermediate in the production of pharmaceuticals, agrochemicals, and other organic compounds. It also serves as a precursor to various polymers and copolymers. The compound is highly reactive and easily polymerizes, making it important to handle with care. N,N-Diallylamine is known to be a skin and eye irritant and can cause respiratory irritation if inhaled. It is important to use proper protective equipment and protocols when handling this chemical.

InChI:InChI=1/C6H11N/c1-3-5-7-6-4-2/h3-4,7H,1-2,5-6H2

Synthetic route

Diallyl-carbamic acid 1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethyl ester → 5,7-Dimethoxy-2-phenylbenzofuran (34911-33-6) + diallylamine (124-02-7)

Conditions	Yield
In benzene Irradiation;	A 96% B 56%

N,N-Diallylpyridine-2-sulfonamide → diallylamine (124-02-7)

Conditions	Yield
With samarium diiodide In tetrahydrofuran for 4h; Ambient temperature;	90%

N-butylamine (109-73-9) + allyl alcohol (107-18-6) → N-allyl-N-butylamine (4538-09-4) + diallylamine (124-02-7)

Conditions	Yield
With ammonium hexafluorophosphate; [Pt(η3-C3H5)(DPP-Xantphos)]PF6 In toluene; acetonitrile at 30℃; for 44h; Inert atmosphere;	A 85% B 4%

hexan-1-amine (111-26-2) + allyl alcohol (107-18-6) → N-allylhexan-1-amine (22774-71-6) + diallylamine (124-02-7)

Conditions	Yield
With ammonium hexafluorophosphate; [Pt(η3-C3H5)(DPP-Xantphos)]PF6 In toluene; acetonitrile at 50℃; for 8h; Inert atmosphere;	A 81% B 7%

allyl alcohol (107-18-6) + benzylamine (100-46-9) → Allylbenzylamine (4383-22-6) + diallylamine (124-02-7)

Conditions	Yield
With ammonium hexafluorophosphate; [Pt(η3-C3H5)(DPP-Xantphos)]PF6 In toluene; acetonitrile at 30℃; for 20h; Inert atmosphere;	A 80% B 7%

N,N-diallyl-2-phenyl-2-propen-1-amine + tert.-butyl lithium (594-19-4) → (4,4-dimethylpent-1-en-2-yl)benzene (7283-47-8) + diallylamine (124-02-7)

Conditions	Yield
Stage #1: N,N-diallyl-2-phenyl-2-propen-1-amine; tert.-butyl lithium In tetrahydrofuran at -78 - 0℃; Stage #2: With water In tetrahydrofuran	A n/a B 79%

N,N-diallyltritylamine → diallylamine (124-02-7)

Conditions	Yield
Stage #1: N,N-diallyltritylamine With naphthalene; lithium In tetrahydrofuran at 0℃; for 6h; Stage #2: With water In tetrahydrofuran at 0 - 20℃;	62%

Diallylcyanamid (538-08-9) → diallylamine (124-02-7)

Conditions	Yield
With sulfuric acid
With sulfuric acid In water at 30℃;

allyl bromide (106-95-6) + 1-amino-2-propene (107-11-9) → diallylamine (124-02-7)

1-amino-2-propene (107-11-9) + 3-chloroprop-1-ene (107-05-1) → diallylamine (124-02-7)

1,2-propanediene (463-49-0) + 1-amino-2-propene (107-11-9) → Triallylamine (102-70-5) + N-allyl(2,3-dimethylene)butylamine (86660-16-4) + Diallyl-(3-methyl-2-methylene-but-3-enyl)-amine (86660-17-5) + Allyl-bis-(3-methyl-2-methylene-but-3-enyl)-amine + diallylamine (124-02-7)

Conditions	Yield
sodium tetrahydroborate; triphenylphosphine; palladium dichloride at 150℃; for 1h; Product distribution; other temperatures, times; reaction with diallyl amine and N-allyl(2,3-dimethylene)butylamine; telomerization of propadiene with allyl amines;

1,2-propanediene (463-49-0) + 1-amino-2-propene (107-11-9) → N-allyl(2,3-dimethylene)butylamine (86660-16-4) + Diallyl-(3-methyl-2-methylene-but-3-enyl)-amine (86660-17-5) + Allyl-bis-(3-methyl-2-methylene-but-3-enyl)-amine + diallylamine (124-02-7)

Conditions	Yield
sodium tetrahydroborate; triphenylphosphine; palladium dichloride at 130℃; for 3h;

1,2-propanediene (463-49-0) → Diallyl-(3-methyl-2-methylene-but-3-enyl)-amine (86660-17-5) + diallylamine (124-02-7)

Conditions	Yield
sodium tetrahydroborate; triphenylphosphine; palladium dichloride at 130℃; for 6h;

(R)-5-Allylaminomethyl-2,7,8-trimethyl-2-((4R,8R)-4,8,12-trimethyl-tridecyl)-chroman-6-ol; hydrobromide + allylHal → diallylamine (124-02-7)

Conditions	Yield
With sodium hydroxide 1.) CH2Cl2, -20 deg C, 10 min, 2.) room temperature, 30 min, 3.) 70 deg C, 1 h; Yield given. Multistep reaction;

ammonia (7664-41-7) + 3-chloroprop-1-ene (107-05-1) → Triallylamine (102-70-5) + 1-amino-2-propene (107-11-9) + diallylamine (124-02-7)

Conditions	Yield
at 97 - 105℃; unter Druck;

3-chloroprop-1-ene (107-05-1) → diallylamine (124-02-7) + allylamine and triallylamine

Conditions	Yield
With ammonia at 97 - 105℃; under 5884.06 - 11032.6 Torr;
With ammonia at 97 - 105℃; under 5884.06 - 11032.6 Torr;

ethanol (64-17-5) + 3-chloroprop-1-ene (107-05-1) → diallylamine (124-02-7) + allylamine and triallylamine

Conditions	Yield
With ammonia at 10℃;

Diallylcyanamid (538-08-9) + diluted alkaline solution → diallylamine (124-02-7)

Conditions	Yield
Hydrolysis;

Diallylcyanamid (538-08-9) + diluted mineral acid → diallylamine (124-02-7)

Conditions	Yield
Hydrolysis;

Triallylamine (102-70-5) → diallylamine (124-02-7) + polymer of acrylaldehyde

Conditions	Yield
With alkaline potassium hexacyanoferrate(III) In ethanol at 25℃; Mechanism; Rate constant; Kinetics; variations in the ionic strength of the reaction medium (cations and anions), varying amount of solvent; ΔG(excit.), ΔH(excit.), ΔS(excit.);

benzyl diallylcarbamate (25070-76-2) → diallylamine (124-02-7)

Conditions	Yield
With naphthalen-1-yl-lithium In tetrahydrofuran at 0℃; for 1h;	62 % Chromat.

3-chloroprop-1-ene (107-05-1) → Triallylamine (102-70-5) + 1-amino-2-propene (107-11-9) + diallylamine (124-02-7)

Conditions	Yield
Stage #1: 3-chloroprop-1-ene With formaldehyd; ammonia In methanol; water at 40 - 70℃; for 6h; Stage #2: With hydroxyammonium sulfate; sulfuric acid In methanol; water at 40℃; for 0.5h; pH=0.8; Stage #3: With sodium hydroxide In methanol; water pH=12; Product distribution / selectivity;
Stage #1: 3-chloroprop-1-ene With ammonia In methanol; water at 40 - 70℃; for 6h; Stage #2: With hydroxyammonium sulfate; sulfuric acid In methanol; water at 40℃; for 0.5h; pH=0.8; Stage #3: With sodium hydroxide In methanol; water pH=12; Product distribution / selectivity;
With ammonium hydroxide at 35℃; for 0.666667h; Temperature;

piperidine (110-89-4) + C13H23NO (26256-86-0) → 1-(piperidin-1-yl)heptan-1-one (18494-53-6) + diallylamine (124-02-7)

Conditions	Yield
With Al2(NMe2)6 In toluene at 90℃; for 16h; Equilibrium constant;

C13H23NO (26256-86-0) + benzyl-methyl-amine (103-67-3) → C15H23NO (1002752-21-7) + diallylamine (124-02-7)

Conditions	Yield
With Al2(NMe2)6 In toluene at 90℃; for 16h; Equilibrium constant;

1,2-propanediene (463-49-0) → Triallylamine (102-70-5) + 1-amino-2-propene (107-11-9) + diallylamine (124-02-7)

Conditions	Yield
With AuC27H42N2(1+)*B(C6F5)4(1-)=(AuC27H42N2)(B(C6F5)4); ammonia In benzene-d6 at -60 - 165℃; Inert atmosphere;
With ammonia; AuC27H42N2(1+)*B(C6F5)4(1-)=(AuC27H42N2)(B(C6F5)4) In benzyl methyl ether; benzene-d6 at -60 - 175℃; Conversion of starting material;

1,2-propanediene (463-49-0) → 1-amino-2-propene (107-11-9) + diallylamine (124-02-7)

Conditions	Yield
With AuC27H42N2(1+)*B(C6F5)4(1-)=(AuC27H42N2)(B(C6F5)4); ammonia In benzene-d6 at -60 - 175℃; Inert atmosphere;

Triallylamine (102-70-5) → acrolein (107-02-8) + diallylamine (124-02-7)

Conditions	Yield
With rhodium(III) 5,10,15,20-tetra(p-sulfonatophenyl)porphyrin; oxygen; trifluoroacetic acid In water at 100℃; under 760.051 Torr; for 2h;

diphenyl diallylphosphoramidate → diallylamine (124-02-7)

Conditions	Yield
Stage #1: diphenyl diallylphosphoramidate With water; monoammonium para-toluenesulfonate; o-phthalic dicarboxaldehyde In acetonitrile at 90℃; for 24h; Sealed tube; Stage #2: With sodium hydroxide In water pH=8 - 9; chemoselective reaction;

Cyclopentene oxide (285-67-6) + diallylamine (124-02-7) → trans-2-(diallylamino)cyclopentanol (77924-51-7)

Conditions	Yield
In ethanol for 24h; Heating;	100%
In ethanol at 95℃; Sealed tube;	100%
With triethylaluminum 1.) toluene, CH2Cl2, 25-30 deg C, 30 min, 2.) room temperature; Yield given. Multistep reaction;

C-phenyl-N-methylnitrone (3376-23-6, 7372-59-0, 59862-60-1) + diallylamine (124-02-7) → trans-2,3-dimethyl-6-phenyl-5-(prop-2-enyl)-1,2,5-oxadiazinane

Conditions	Yield
In chloroform at 60℃; for 72h;	100%
In chloroform at 60℃; for 72h; Cyclization;	100%

diallylamine (124-02-7) + ethyl trans-3-phenyl-1-oxirane-2-carboxylate (2272-55-1) → ethyl (2R*,3R*)-3-chloro-2-(diallylamino)-3-phenylpropanoate

Conditions	Yield
Stage #1: diallylamine; ethyl trans-3-phenyl-1-oxirane-2-carboxylate In ethanol for 12h; Ring cleavage; addition; Heating; Stage #2: With methanesulfonyl chloride; triethylamine In dichloromethane at 0 - 20℃; for 3h; Rearrangement; chlorination;	100%

Cinnamyl acetate (21040-45-9) + diallylamine (124-02-7) → (E)-N,N-diallyl-3-phenylprop-2-en-1-amine (155687-70-0)

Conditions	Yield
bis(η3-allyl-μ-chloropalladium(II)); (1RS,2RS,3SR,4SR)-1,2,3,4-tetrakis((diphenylphosphanyl)methyl)cyclopentane In water at 25℃; for 40h;	100%
bis(η3-allyl-μ-chloropalladium(II)); Tedicyp In water at 25℃; for 40h;	99%

bicyclo(3.2.0)hept-2-en-6-one (925211-06-9, 925211-07-0) + 5-phenyl-[1,2,4]triazine-3-carboxylic acid ethyl ester (126421-91-8) + diallylamine (124-02-7) → [1RS,2RS,3SR,7SR,8SR,11SR,12SR]-9-allyl-12-(ethoxycarbonyl)-14-phenyl-9,13-diazapentacyclo[9.3.1.02,8.03,7.08,12]pentadecadi-4,13-ene

Conditions	Yield
With 4 A molecular sieve In chloroform for 21h; Heating;	100%
With 4 A molecular sieve In chloroform for 21h; Heating;	100%

cyclobutanone (1191-95-3) + 5-phenyl-[1,2,4]triazine-3-carboxylic acid ethyl ester (126421-91-8) + diallylamine (124-02-7) → [1RS,2RS,5SR,8SR,9SR]-6-allyl-9-(ethoxycarbonyl)-11-phenyl-6,10-diazatetracyclo[6.2.1.02,5.05,9]dodec-10-ene

Conditions	Yield
With 4 A molecular sieve In chloroform for 22h; Heating;	100%
With 4 A molecular sieve In chloroform for 22h; Heating;	99%

wortmannin (19545-26-7) + diallylamine (124-02-7) → acetic acid 4-diallylaminomethylene-6-hydroxy-1α-methoxymethyl-10β,13β-dimethyl-3,7,17-trioxo-1,3,4,7,10,11β,12,13,14α,15,16,17-dodecahydro-2-oxa-cyclopenta[a]phenanthren-11-yl ester

Conditions	Yield
In dichloromethane at 20℃; for 1h;	100%
In dichloromethane at 20℃; for 1h;	68%

diallylamine (124-02-7) + (1R,2S,4S)-(+)-(N-bromoacetyl)bornane-10,2-sultam (252577-46-1) → (1R,2S)-N-[2'-(diallylamino)acetyl]bornane-10,2-sultam (844498-35-7)

Conditions	Yield
With potassium carbonate In acetone at 20℃;	100%

L-N-Boc-Ala (15761-38-3) + diallylamine (124-02-7) → (S)-tert-butyl 1-(diallylamino)-1-oxopropan-2-ylcarbamate (950608-92-1)

Conditions	Yield
Stage #1: L-N-Boc-Ala With dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 0.5h; Inert atmosphere; Stage #2: diallylamine In dichloromethane at 20℃; for 12h; Inert atmosphere;	100%
With dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 12h;

17-formylwortmannin (884540-65-2) + diallylamine (124-02-7) → (1E,4S,4aR,5R,6aS,7S)-1-[(diallylamino)methylene]-7-(formyloxy)-11-hydroxy-4-(methoxymethyl)-4a,6a-dimethyl-2,10-dioxo-1,2,4,4a,5,6,6a,7,8,9,9a,10-dodecahydroindeno[4,5-h]isochromen-5-yl acetate

Conditions	Yield
In dichloromethane for 0.5h;	100%

C12H12FNO6 (926648-02-4) + diallylamine (124-02-7) → C18H22N2O6 (926648-05-7)

Conditions	Yield
With triethylamine In acetonitrile at 20℃; for 1.5h;	100%

diallylamine (124-02-7) + Trichloroacetyl chloride (76-02-8) → N,N-diallyl-α,α,α-trichloroacetamide (39089-57-1)

Conditions	Yield
With pyridine In dichloromethane at 0 - 20℃; for 2h;	100%
With pyridine In dichloromethane at 20℃; for 2h;	94%

2,3-dihydro-2H-furan (1191-99-7) + carbon disulfide (75-15-0) + diallylamine (124-02-7) → tetrahydrofuran-2-yl diallylcarbamodithioate (1239488-67-5)

Conditions	Yield
In water at 20℃; for 16h; regiospecific reaction;	100%

oxalyl dichloride (79-37-8) + Benzoylformic acid (611-73-4) + diallylamine (124-02-7) → 1-phenyl-2-(diallylamino)ethane-1,2-dione

Conditions	Yield
Stage #1: oxalyl dichloride; Benzoylformic acid With copper diacetate; N,N-dimethyl-formamide In dichloromethane at 20℃; for 2h; Stage #2: diallylamine With triethylamine In dichloromethane	100%

N-phenyl-N-methylcarbamoyl chloride (4285-42-1) + diallylamine (124-02-7) → 1,1-diallyl-3-methyl-3-phenyl-urea

Conditions	Yield
With dmap; triethylamine In 1,2-dichloro-ethane Reflux; Inert atmosphere;	100%

2-vinylpyridine (100-69-6) + carbon disulfide (75-15-0) + diallylamine (124-02-7) → 2-(pyridin-2-yl)ethyl diallylcarbamodithioate

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

Nonanoyl chloride (764-85-2) + diallylamine (124-02-7) → N,N-diallylnonanamide

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 14h; Inert atmosphere;	100%

2-bromo-4-methoxybenzenesulfonyl chloride (23095-16-1) + diallylamine (124-02-7) → N,N-diallyl-2-bromo-4-methoxybenzenesulfonamide

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃; for 15h;	100%

2-bromo-5-methoxybenzenesulfonyl chloride (179251-57-1) + diallylamine (124-02-7) → N,N-diallyl-2-bromo-5-methoxybenzenesulfonamide

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃; for 15h;	100%

phenyl isocyanate (103-71-9) + diallylamine (124-02-7) → 1,1-diallyl-3-phenylurea (100615-32-5)

Conditions	Yield
In diethyl ether at 20℃; for 0.166667h;	99%
With 1,6-anhydro-3,4-dideoxy-β-D-glycero-hexopyranos-2-ulose at 0 - 20℃; for 1h;	99%
With triethylamine In dichloromethane at 0 - 20℃; for 1h; Inert atmosphere;	95%

acryloyl chloride (814-68-6) + diallylamine (124-02-7) → N,N-diallylacrylamide (3085-68-5)

Conditions	Yield
With triethylamine In benzene at 0℃; for 0.5h;	99%
With trimethylamine In ethyl acetate at 23℃; for 18h; Cooling with ice;	75%
With triethylamine In dichloromethane for 24h; Ambient temperature;	71%

acrolein (107-02-8) + diallylamine (124-02-7) → 3-(N,N-diallylamino)-propanal (142138-16-7)

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 0℃; Michael addition;	99%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at -15℃; for 0.166667h;	95%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at -15℃; for 0.666667h;

di-tert-butyl dicarbonate (24424-99-5) + diallylamine (124-02-7) → tert-butyl diallylcarbamate (151259-38-0)

Conditions	Yield
In methanol at 0 - 20℃; for 1h;	99%
With iodine at 20℃; for 0.5h;	95%
In cyclohexane at 20℃; for 20h;	93%

4-chlorobenzoyl chloride (586-75-4) + diallylamine (124-02-7) → N,N-diallyl-4-bromobenzamide (5866-96-6)

Conditions	Yield
Stage #1: 4-chlorobenzoyl chloride With pyridine; Merrifield's resin-bound 6-methyl-2-thiouracil In dichloromethane at 80℃; for 0.0833333h; microwave irradiation; Stage #2: diallylamine In dichloromethane at 80℃; for 0.0833333h; microwave irradiation;	99%
With triethylamine In dichloromethane at 0 - 20℃; for 1h; Inert atmosphere;	97%
With triethylamine In dichloromethane at 0 - 20℃;	89%

2-bromo-5-methoxy-benzoic acid (22921-68-2) + diallylamine (124-02-7) → N,N-diallyl-2-bromo-5-methoxy-benzamide (851297-49-9)

Conditions	Yield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0 - 20℃;	99%

furfural (98-01-1) + diallylamine (124-02-7) → trans-4,5-bis(diallylamine)cyclopent-2-enone

Conditions	Yield
With 4C14H11NO3(2-)*2Ni(2+)*2Dy(3+)*2Cl(1-)*2C2H3N In acetonitrile at 20℃; for 24h; Reagent/catalyst; Molecular sieve;	99%
In water at 60℃; for 0.0833333h; Microwave irradiation;	93%
With 4 A molecular sieve; dysprosium(III) trifluoromethanesulfonate In acetonitrile at 20℃; for 16h;	82%

3-chloro-3-oxopropanoic acid methyl ester (37517-81-0) + diallylamine (124-02-7) → methyl 3-(N,N-diallylamino)-3-oxopropanoate (1193366-04-9)

Conditions	Yield
In dichloromethane at 10 - 20℃;	99%

di-tert-butyl dicarbonate (24424-99-5) + diallylamine (124-02-7) → tert-butyl di(but-3-en-1-yl)carbamate (1211531-07-5)

Conditions	Yield
In methanol at 0 - 20℃;	99%

rac-(E)-1,3-diphenyl-3-acetoxy-prop-1-ene (87751-69-7) + diallylamine (124-02-7) → (S,E)-N,N-diallyl-(1,3-diphenyl-2-propenyl)amine (1202053-74-4)

Conditions	Yield
With C32H31NO2PPd(1+)*F6P(1-); potassium acetate; N,O-bis-(trimethylsilyl)-acetamide at 20℃; for 4h; Inert atmosphere; Neat (no solvent); enantioselective reaction;	99%
With N,O-bis-(trimethylsilyl)-acetamide; bis(η3-allyl-μ-chloropalladium(II)); 1-benzyl-5-(((4R,5R)-2-(2-(diphenyl-phosphino)phenyl)-4,5-diphenyl-4,5-dihydro-1H-imidazol-1-yl)methyl)-1H-1,2,3-triazole; potassium acetate In dichloromethane for 24h; Inert atmosphere; Reflux; optical yield given as %ee; enantioselective reaction;

1-ethynyl cobaltocenium hexafluorophosphate (131276-87-4) + diallylamine (124-02-7) → C18H21CoN(1+)*F6P(1-)

Conditions	Yield
In neat (no solvent) at 35℃; for 1h; Solvent; Time;	99%

Upstream product

• 538-08-9 Diallylcyanamid 
• 106-95-6 allyl bromide 
• 107-11-9 1-amino-2-propene 
• 107-05-1 3-chloroprop-1-ene 
• 463-49-0 1,2-propanediene 
• 7664-41-7 ammonia 
• 64-17-5 ethanol 
• 102-70-5 Triallylamine 
• 25070-76-2 benzyl diallylcarbamate 
• 594-19-4 tert.-butyl lithium 
• 110-89-4 piperidine 
• 26256-86-0 C₁₃H₂₃NO 
• 103-67-3 benzyl-methyl-amine 
• 111-26-2 hexan-1-amine 

Downstream Products

• 17719-79-8 (N,N-diallyl)-2-aminoethanol 
• 5842-11-5 2-(Diallyl)-aminoethanthiol 
• 25077-82-1 1,1-Diallyl-1,4-diaza-butan 
• 857977-79-8 N²,N²-diallyl-6-chloro-[1,3,5]triazine-2,4-diyldiamine 
• 60676-77-9 N,N-diallyltryptamine 
• 110246-74-7 N,N-diallyl-DL-alanine-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-methyl-amide] 
• 60728-51-0 N,N-diallyl ethyl carbamate 
• 4383-26-0 N,N-di-2-propenylbenzylamine 
• 78176-88-2 3-diallylamino-cyclohex-2-enone 
• 101255-81-6 1-diallylamino-3-o-tolyloxy-propan-2-ol 
• 100615-32-5 1,1-diallyl-3-phenylurea 
• 94037-63-5 diallyl-amidophosphoric acid diethyl ester 
• 93-71-0 allidochlor 
• 60277-03-4 N,N-diallyl-2-bromoacetamide 

Relevant articles and documents

Preparation method of diallylamine and hydrochloride thereof

The invention belongs to the technical field of organic synthesis, and in particular relates to a preparation method of diallylamine and hydrochloride thereof. The preparation method comprises the following steps: inputting ammonia water into a reaction kettle, adding a catalyst, dropwise adding 3-chloropropene at a constant temperature and a constant pressure, heating the mixture to 50-55 DEG C after dropwise addition, keeping the temperature for 1 hour, and reducing the temperature to 35-40 DEG C to obtain slurry; extracting the slurry to a distilling kettle, adding sodium hydroxide and a byproduct ammonium chloride into the distilling kettle to react, absorbing generated ammonia water with water and reusing the same, neutralizing the same, starting distillation till a water phase is obtained, adding caustic soda flakes to dehydrate, cyclically using the dehydrated alkaline liquor t o obtain a diallylamine coarse product; and inputting the coarse product into a rectifying kettle, taking a small amount of precomponent first, then receiving diallylamine, and returning the precomponent to a reaction kettle to be used. The diallylamine and hydrochloride thereof are prepared by adopting an amination process, so that the method is safe and is guaranteed, and meanwhile, excessive ammonia water and alkaline water are fully recycled, so that the preparation method is low in energy consumption and little in pollution, and the three wastes can be recycled.

O -Phthalaldehyde catalyzed hydrolysis of organophosphinic amides and other P(O)-NH containing compounds

Over 50 years ago, Jencks and Gilchrist showed that formaldehyde catalyses the hydrolysis of phosphoramidate through electrophilic activation, induced by covalent attachment to its nitrogen atom. Given our interest in the use of aldehydes as catalysts, this work was revisited to identify a superior catalyst, o-phthalaldehyde, which facilitates hydrolyses of various organophosphorus compounds bearing P(O)-NH subunits under mild conditions. Interestingly, chemoselective hydrolysis of the P(O)-N bonds could be accomplished in the presence of P(O)-OR bonds.

GOLD CATALYZED HYDROAMINATION OF ALKYNES AND ALLENES

Methods are provided for the catalytic hydroamination of compounds having an alkyne or allene functional group, in which the compound is contacted with ammonia or an amine in the presence of a catalytic amount of a gold complex under conditions sufficient for hydroamination to occur.