100622-07-9Relevant academic research and scientific papers
Nitroepoxide ring opening with thionucleophiles in water: Synthesis of α-xanthyl ketones, β-keto sulfones and β-keto sulfonic acids
Badali, Elham,Habibi, Azizollah,Rahimzadeh, Hossein,Sharifi, Ali,Ziyaei Halimehjani, Azim
supporting information, p. 4983 - 4987 (2020/07/30)
Nitroepoxide ring opening with thionucleophiles such as potassium xanthates, sodium aryl sulfinates and sodium bisulfite in water is investigated. It provides a direct and green route for the synthesis of α-xanthyl-α-aryl-2-propanones (P2P-xanthate derivatives), β-keto sulfones and β-keto sulfonic acids. High to excellent yields, performing the reaction in water under catalyst-free conditions, and easy work-up are the main advantages of this protocol.
