100655-82-1Relevant academic research and scientific papers
α-FLUORO- AND α,α-DIFLUOROALKANALS BY SUBSTITUTION OF VICINAL BROMOFLUOROALKANES AND SUBSEQUENT PUMMERER REARRANGEMENT
Suga, Hiroaki,Schlosser, Manfred
, p. 4261 - 4264 (2007/10/02)
2-Fluoro- or 2,2-difluoro-1-bromoalkanes readily ondergo nucleophilic substitution by sodium thiophenolate to give 2-fluoro- or 2,2-difluoroalkyl phenyl sulfides (1a-1c).The latter may be oxidized to the corresponding sulfoxides (2a-2c).Heating with aceti
The Preparation of β-Fluoro Thioethers
Purrington, Suzanne T.,Correa, Itzela D.
, p. 1080 - 1083 (2007/10/02)
Addition of benzenesulfenyl chloride to electron-rich olefins in the presence of silver produces β-fluoro thioethers.The trans adducts could also be prepared from β-chloro thioethers and silver fluoride.
