1006904-67-1

Basic information

• Product Name: HEXAMETHYLGUANIDINIUM TRIFLUOROMETHANOLATE
• Synonyms: HEXAMETHYLGUANIDINUM-TRIFLUOROMETHANOLATE;HEXAMETHYLGUANIDINIUM TRIFLUOROMETHANOLATE;HEXAMETHYLGUANIDINIUM TRIFLUOROMETHYLATE;Methanaminium, N-[bis(dimethylamino)methylene]-N-methyl-, salt with 1,1,1-trifluoromethanol (1:1);bis(dimethylamino)methylidene-dimethylazanium:trifluoromethanolate
• CAS NO: 1006904-67-1
• Molecular Formula: CF₃O*C₇H₁₈N₃
• Molecular Weight: 229.24
• Mol File: 1006904-67-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: HEXAMETHYLGUANIDINIUM TRIFLUOROMETHANOLATE(CAS DataBase Reference)
• NIST Chemistry Reference: HEXAMETHYLGUANIDINIUM TRIFLUOROMETHANOLATE(1006904-67-1)
• EPA Substance Registry System: HEXAMETHYLGUANIDINIUM TRIFLUOROMETHANOLATE(1006904-67-1)

Safety Data

• Statements: 34
• Safety Statements: 26-36/37/39
• RIDADR: 1759
• Hazardous Substances Data: 1006904-67-1(Hazardous Substances Data)

Upstream product

• 478945-43-6 C₃H₉F₂Si^(1-)*C₇H₁₈N₃⁽¹⁺⁾ 
• 3582-05-6 trifluoromethyl trifluoromethanesulfonate 
• 353-50-4 Carbonyl fluoride 

Downstream Products

• 1006904-68-2 ethyl-2-(trifluoromethoxy)propanoate 
• 349-43-9 ethyl 2-fluoropropionate 

Relevant articles and documents

Versatile application of trifluoromethyl triflate

Hydrolytically stable and easy to handle trifluoromethyl triflate was found to be a liquid reservoir of 'masked' difluorophosgene. Anhydrous F- sources cleave the S-O bond in trifluoromethyl triflate yielding quantitatively the trifluoromethanolate salts, being useful trifluoromethoxy group carriers. Reaction of trifluoromethanolates with in situ generated from o-trimethylsilylphenyl triflate benzyne leads to (trifluoromethoxy)benzene and fluorobenzene (ratio 85:15). Whereas an addition of trifluoromethanethiolate anion across a triple bond of benzyne leads to [(trifluoromethyl)sulfanyl]benzene solely.