169059-34-1

Basic information

• Product Name: (1-(4-chlorophenyl)ethyl)(phenyl)sulfane
• Synonyms: (1-(4-chlorophenyl)ethyl)(phenyl)sulfane
• CAS NO: 169059-34-1
• Molecular Weight: 248.776
• Mol File: 169059-34-1.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: (1-(4-chlorophenyl)ethyl)(phenyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (1-(4-chlorophenyl)ethyl)(phenyl)sulfane(169059-34-1)
• EPA Substance Registry System: (1-(4-chlorophenyl)ethyl)(phenyl)sulfane(169059-34-1)

Safety Data

• Hazardous Substances Data: 169059-34-1(Hazardous Substances Data)

Upstream product

• 882-33-7 diphenyldisulfane 
• 108-98-5 thiophenol 
• 1073-67-2 4-vinylbenzyl chloride 
• 104-93-8 p-methylanizole 
• 75230-50-1 p-chloroacetophenone tosylhydrazone 
• 3391-10-4 1-(p-chlorophenyl)ethyl alcohol 
• 1007-27-8 (phenylthio)trimethylstannane 
• 14804-61-6 1-(1-bromoethyl)-4-chlorobenzene 
• 4848-62-8 Trimethyl(phenylthio)germane 
• 99-91-2 para-chloroacetophenone 

Downstream Products

• 20001-65-4 1-chloro-4-(1-chloroethyl)benzene 

Relevant articles and documents

Zinc Chloride Mediated Nucleophilic Substitution: Amination and Thioetherification of Alcohols at Room Temperature

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Highly Efficient and Chemoselective Tertiary and Secondary Benzylation of Thiols Catalyzed by Indium(III) Triflate

Several examples of nucleophilic substitution reactions of compounds that have good leaving groups have been previously reported, but the direct use of simple alcohols still remains a challenge because of the poor leaving ability of the hydroxy group. Herein, an efficient and highly chemoselective method for the S-benzylation of a wide range of aromatic and aliphatic thiols has been accomplished in the presence of catalytic amounts (0.1–0.2 mol-%) of indium(III) triflate. Our approach is atom efficient (water is the only byproduct) and suitable to obtain the corresponding unsymmetrical thioethers in excellent yields (up to 99 %). The low loading of catalyst that are needed to obtain extraordinarily high chemoselectivities and the generality of the reaction make this approach unique.

Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds

A new approach is presented to form self-supported bimetallic nanosized solids with acid and redox catalytic properties. They are water-, air- and H2-stable, and are able to activate demanding C-C and C-H reactions. A detailed mechanistic study on the formation of the Ag-Fe bimetallic system shows that a rapid redox-coupled sequence between Ag+, O2 (air) and Fe2+ occurs, giving monodisperse Ag nanoparticles supported by O-bridged diatomic Fe3+ triflimides. The system can be expanded to Ag nanoparticles embedded within a matrix of Cu2+, Bi3+ and Yb3+ triflimide.