9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane is a chemical compound that features a bicyclo[3.3.1]nonane core with a trimethylsilanyl-but-2-enyl group attached to the 9-position. 9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane is known for its unique structure and reactivity, particularly in organic synthesis.
100701-75-5
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Basic information
- Product Name: 9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane
- Synonyms: 9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane
- CAS NO:100701-75-5
- Molecular Formula:
- Molecular Weight: 248.292
- EINECS: N/A
- Product Categories: N/A
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Chemical Properties
- Melting Point: N/A
- Boiling Point: N/A
- Flash Point: N/A
- Appearance: N/A
- Density: N/A
- Refractive Index: N/A
- Storage Temp.: N/A
- Solubility: N/A
- CAS DataBase Reference: 9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane(CAS DataBase Reference)
- NIST Chemistry Reference: 9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane(100701-75-5)
- EPA Substance Registry System: 9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane(100701-75-5)
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Safety Data
- Hazard Codes: N/A
- Statements: N/A
- Safety Statements: N/A
- WGK Germany:
- RTECS:
- HazardClass: N/A
- PackingGroup: N/A
- Hazardous Substances Data: 100701-75-5(Hazardous Substances Data)
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100701-75-5 Usage
Uses
Used in Organic Synthesis:9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane is used as an anti-(Z)-selective allylation reagent for aldehydes and pyruvates. This selective reactivity allows for the efficient synthesis of (Z)-2-butenylsilane compounds, which are valuable intermediates in the preparation of various organic molecules.
Used in Stereoselective Synthesis:
In the field of stereoselective synthesis, 9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane plays a crucial role in the preparation of (Z)-configured compounds. Its ability to selectively form (Z)-2-butenylsilane products makes it a valuable tool for chemists looking to control the stereochemistry of their reactions.
Physical properties:
9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane has a boiling point of 85–87 °C at a pressure of 0.03 mmHg, indicating that it is a volatile compound under reduced pressure conditions. This property can be useful for its purification and handling in chemical processes.
Check Digit Verification of cas no
The CAS Registry Mumber 100701-75-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,0,7,0 and 1 respectively; the second part has 2 digits, 7 and 5 respectively.Calculate Digit Verification of CAS Registry Number 100701-75:
(8*1)+(7*0)+(6*0)+(5*7)+(4*0)+(3*1)+(2*7)+(1*5)=65
65 % 10 = 5
So 100701-75-5 is a valid CAS Registry Number.
100701-75-5Upstream product
100701-75-5Downstream Products
- 79139-02-9 (E)-2-methyl-1-phenyl-4-(trimethylsilyl)-3-buten-1-ol
- 79139-02-9 (Z)-2-Methyl-1-phenyl-4-trimethylsilanyl-but-3-en-1-ol
- 79139-02-9 (1R*,2R*,3Z)-2-methyl-1-phenyl-4-trimethylsilyl-3-buten-1-ol
- 79139-07-4 (1S,2R)-1-Phenyl-2-((2R,3S)-3-trimethylsilanyl-oxiranyl)-propan-1-ol
- 79139-07-4 (1R,2S)-1-Phenyl-2-((2R,3S)-3-trimethylsilanyl-oxiranyl)-propan-1-ol
- 79152-53-7 (1E,5Z)-(3R,4S)-4-Methyl-1-phenyl-6-trimethylsilanyl-hexa-1,5-dien-3-ol
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9-((E)-1-Trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane
