79139-02-9Relevant academic research and scientific papers
Refunctionalization of Homoallylic Alcohols Containing a Vinylic Chlorine Atom
Hoffmann, Reinhard W.,Giesen, Volker,Fuest, Marcus
, p. 629 - 640 (2007/10/02)
The chlorine atoms in Z-substituted vinyl chlorides 1, 5, 7 and 14 have been replaced by alkyl, vinyl and (trimethylsilyl)methyl groups to give the alkenes 3, 4, the dienes 9, 10, 15, or the allylsilanes 8.The latter have been transformed stereoselectivel
Regio- and stereo-selective reactions of trimethylsilyl-substituted allyl-chromium reagents with aldehydes
Hodgson,Wells
, p. 4761 - 4762 (2007/10/02)
The use of the title compounds in the syntheses of anti-β-hydroxysilanes (3) and vinylsilanes (13-14) is described.
ORGANIC SYNTHESIS WITH REAGENTS DERIVED FROM 3R3SiMgMe AND MnCl2
Fugami, Keigo,Hibino, Jun-ichi,Nakatsukasa, Shigeki,Matsubara, Seijiro,Oshima, Koichiro,et al.
, p. 4277 - 4292 (2007/10/02)
Synthetically useful reactions mediated by reagents derived from 3 equiv. of R3SiMgMe and MnCl2 are disclosed. (1) The manganese species reacted with terminal acetylenes to give 1,2-disilylated 1-alkenes.Mono- and bis(trimethylsilyl)acetylenes gave tri- a
