1007117-84-1Relevant academic research and scientific papers
Palladium-catalyzed nonalternating copolymerization of ethene and carbon monoxide: Scope and mechanism
Luo, Rong,Newsham, David K.,Sen, Ayusman
, p. 6994 - 7000 (2010/04/04)
A series of nonalternating ethene/carbon monoxide copolymers with very low carbon monoxide content were synthesized using a neutral palladium catalyst bearing a phosphine-sulfonate ligand. The ratio of the binding affinities of carbon monoxide and ethene
Inhibitory role of carbon monoxide in palladium(II)-catalyzed nonalternating ethene/carbon monoxide copolymerizations and the synthesis of polyethene-block-poly(ethene-alt-carbon monoxide)
Newsham, David K.,Borkar, Sachin,Sen, Ayusman,Conner, David M.,Goodall, Brian L.
, p. 3636 - 3638 (2008/10/09)
We report the first well-defined palladium-based system for the living homopolymerization of ethene, as well as the living copolymerization of ethene with carbon monoxide. We demonstrate this by the synthesis of polyethene-block-poly-(ethene-alt-carbon mo
Ligand effects in the non-alternating CO-ethylene copolymerization by palladium(ii) catalysis
Bettucci, Lorenzo,Bianchini, Claudio,Claver, Carmen,Suarez, Eduardo J. Garcia,Ruiz, Aurora,Meli, Andrea,Oberhauser, Werner
, p. 5590 - 5602 (2008/09/17)
In this paper we report on a comparative study of the non-alternating CO-C2H4 copolymerization catalyzed by neutral Pd II complexes with the phosphine-sulfonate ligands bis(o-methoxyphenyl)phosphinophenylenesulfonate and b
