1007229-13-1Relevant academic research and scientific papers
All-carbon intramolecular conjugate displacement reactions: An effective route to carbocycles
Prabhudas, Bodhuri,Clive, Derrick L. J.
, p. 9295 - 9297 (2008/12/22)
(Chemical Equation Presented) Working together: Synergy between Michael addition and SN2′ displacement allows stabilized carbanions or the nucleophilic carbon atoms of enamines to undergo intramolecular addition to an α,β-unsaturated ester unit bearing an allylic leaving group to generate unsaturated carbocycles (see scheme). The starting esters are available by a selenium-based alternative to the classical Baylis-Hillman reaction, and complex structures can be assembled.
