1007348-54-0Relevant academic research and scientific papers
Reduction of CO2 to CO using low-coordinate iron: Formation of a four-coordinate iron dicarbonyl complex and a bridging carbonate complex
Sadique, Azwana R.,Brennessel, William W.,Holland, Patrick L.
, p. 784 - 786 (2008)
A reduced diiron(I) complex reacts with CO2 to give two iron-containing products. One product has a carbonate bridge, which isomerizes rapidly at -70°C and may be derived from an oxodiiron intermediate. The formation of this product releases free CO, which leads to a four-coordinate iron dicarbonyl complex. This product is the first crystallographically characterized example of a four-coordinate iron dicarbonyl species, a moiety that may be present in the active site of Hmd ( iron-sulfur cluster free ) hydrogenase.
