1007386-82-4Relevant academic research and scientific papers
Molecular structure-intersystem crossing relationship of heavy-atom-free bodipy triplet photosensitizers
Ji, Shaomin,Ge, Jie,Escudero, Daniel,Wang, Zhijia,Zhao, Jianzhang,Jacquemin, Denis
, p. 5958 - 5963 (2015)
A thiophene-fused BODIPY chromophore displays a large triplet-state quantum yield (φT = 63.7%). In contrast, when the two thienyl moieties are not fused into the BODIPY core, intersystem crossing (ISC) becomes inefficient and φT remains low (φT = 6.1%). First-principles calculations including spin-orbit coupling (SOC) were performed to quantify the ISC. We found larger SOC and smaller singlet-triplet energy gaps for the thiophene-fused BODIPY derivative. Our results are useful for studies of the photochemistry of organic chromophores.
Efficient light absorbers based on thiophene-fused boron dipyrromethene (BODIPY) dyes
Tanaka, Kazuo,Yamane, Honami,Yoshii, Ryousuke,Chujo, Yoshiki
, p. 2715 - 2719 (2013)
We present the development of the thiophene-fused boron dipyrromethene derivatives as efficient light absorbers. The two strategies for the evolution of the optical properties such as the peak positions of absorption wavelengths and molar extinct coeffici
FLUORO-SUBSTITUTED INHIBITORS OF D-AMINO ACID OXIDASE
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Page/Page column 48, (2008/06/13)
This invention provides novel inhibitors of the enzyme D-amino acid oxidase as well as pharmaceutical compositions including the compounds of the invention. The invention also provides methods for the treatment and prevention of neurological disorders, such as neuropsychiatric and neurodegenerative diseases, as well as pain, ataxia and convulsion. The compounds of the invention have the general structure: wherein A is NH or S. Q is a member selected from CR1 and N. X and Y are members independently selected from O, S, CR2, N and NH. R1, R2 and R4 are members independently selected from H and F, provided that at least one member selected from R1, R2 and R4 is F. R6 is a member selected from O?X+ and OH, wherein X+ is a positive ion, which is a member selected from inorganic positive ions and organic positive ions.
