1007389-77-6Relevant academic research and scientific papers
Cascade radical reaction of substrates with a carbon-carbon triple bond as a radical acceptor
Miyabe, Hideto,Asada, Ryuta,Takemoto, Yoshiji
supporting information, p. 1148 - 1155 (2013/07/26)
The limitation of hydroxamate ester as a chiral Lewis acid coordination moiety was first shown in an intermolecular reaction involving a radical addition and sequential allylation processes. Next, the effect of hydroxamate ester was studied in the cascade
Polarity-mismatched addition of electrophilic carbon radicals to an electron-deficient acceptor: Cascade radical addition-cyclization-trapping reaction
Yoshioka, Eito,Kohtani, Shigeru,Sawai, Kaori,Kentefu,Tanaka, Eri,Miyabe, Hideto
, p. 8588 - 8604,17 (2020/09/15)
The polarity-mismatched perfluoroalkyl radical addition to electron-deficient alkenes was studied. For this study, several substrates having two polarity-different radical acceptors were employed to investigate the regiochemical courses of cascade reactio
A dramatic effect of double bond configuration in N-oxy-3-aza Cope rearrangements-a simple synthesis of functionalised allenes
Pinto, Luis F.V.,Glória, Paulo M.C.,Gomes, Mário J.S.,Rzepa, Henry S.,Prabhakar, Sundaresan,Lobo, Ana M.
experimental part, p. 3446 - 3449 (2009/09/25)
The first examples of low temperature N-oxy-3-aza Cope rearrangements, leading to functionalised allenes are described, where the Z-configuration of the enaminic double bond in the rearranging system proves critical.
Enantioselective cascade radical addition-cyclization-trapping reactions
Miyabe, Hideto,Asada, Ryuta,Toyoda, Akira,Takemoto, Yoshiji
, p. 5863 - 5866 (2007/10/03)
(Chemical Equation Presented) In addition: The chiral Lewis acid mediated radical addition-cyclization-trapping reaction of a hydroxamate ester with two radical acceptors provides a cascade approach for the asymmetric synthesis of various γ-lactams (see s
