10075-73-7Relevant articles and documents
Ni-Catalyzed cross-coupling of aryl thioethers with alkyl Grignard reagents via C-S bond cleavage
Zhu, Dan,Shi, Lei
, p. 9313 - 9316 (2018)
A Ni-catalyzed cross-coupling of aryl thioethers with alkyl Grignard reagents, accompanied by the cleavage of the C(aryl)-SMe bond, has been presented. This method is distinguished by its mild conditions and moderate functional group tolerance, such as hydroxyl, halogen, and heterocycles, which should provide a straightforward access to the modification of sulfur-containing molecules.
Through-bond interaction between sulfonium and sulfenyl sulfur atoms having anthracene and naphthalene spacers
Koyama, Emiko,Kobayashi, Kenji,Horn, Ernst,Furukawa, Naomichi
, p. 8833 - 8836 (1999)
The reaction of 9-(methylsulfinyl)-10-(methylthio)anthracene with trifluoroacetic anhydride followed by quenching with aqueous NaHCO3 gives 9,9-bis(methylthio)-10-anthraquinone. The dithia dication and/or the corresponding carbodication via thr
Thioether-Directed Peri-Selective C-H Arylation under Rhodium Catalysis: Synthesis of Arene-Fused Thioxanthenes
Moon, Sanghun,Nishii, Yuji,Miura, Masahiro
supporting information, p. 233 - 236 (2019/01/10)
A rhodium-catalyzed direct C-H arylation of naphthalene and anthracene was developed with the assistance of a thioether directing group. The reaction proceeded with exclusive peri-selectivity, and the series of coupling products were readily transformed i
Organocatalytic visible light mediated synthesis of aryl sulfides
Majek, Michal,Von Wangelin, Axel Jacobi
supporting information, p. 5507 - 5509 (2013/06/27)
Photo-sensitized synthesis of arylsulfides from arenediazonium salts in the presence of eosin Y has been developed. This protocol exhibits high functional group tolerance and a wide substrate scope and is an attractive alternative to the thermal reaction that involves explosive intermediates.