10075-91-9Relevant academic research and scientific papers
Synthesis of sulfur-containing aryl and heteroaryl vinyls via Suzuki-Miyaura cross-coupling for the preparation of SERS-active polymers
Perez-Pineiro, Rolando,Dai, Sheng,Alvarez-Puebla, Ramon,Wigginton, James,Al-Hourani, Baker Jawabrah,Fenniri, Hicham
, p. 5467 - 5469 (2009)
The preparation of sulfur-containing aryl and heteroaryl vinyl co-monomers via Suzuki-Miyaura cross-coupling between the corresponding mercaptomethyl arylboronates and in situ-generated vinyl bromides is described. Surface-enhanced Raman scattering (SERS) studies of the target compounds on gold nanoparticles confirmed their potential as spectroscopic tags in the fabrication of SERS-encoded polymers for combinatorial screening and biomedical diagnostics.
Pd-catalyzed synthesis of biphenyls with methylthio group
Zhang, Zhiqiang,Hu, Zhizhi,Yu, Zhixiao,Chi, Haijun,Lei, Peng,Wang, Yue,He, Ren
, p. 683 - 690 (2007/10/03)
The synthesis of unsymmetrical biaryls with a methylthio group is achieved using the air-stable palladium-phosphinous acid complexes, [(t-Bu)2P(OH)]2 PdCl2 (POPd), as the catalyst. A great variety of substituted bromobenzenes having electron-withdrawing and electron-donating functional groups in para and meta positions have been successfully coupled with 3-methylthiophenylboronic acid. Copyright Taylor & Francis Group, LLC.
