100762-19-4

Basic information

• Product Name: p-methylphenylsulfonyl 2,3,4,6-tetra-O-acetyl-1-deoxy-β-D-galactopyranoside
• Synonyms: p-methylphenylsulfonyl 2,3,4,6-tetra-O-acetyl-1-deoxy-β-D-galactopyranoside
• CAS NO: 100762-19-4
• Molecular Weight: 486.497
• Mol File: 100762-19-4.mol

Chemical Properties

• CAS DataBase Reference: p-methylphenylsulfonyl 2,3,4,6-tetra-O-acetyl-1-deoxy-β-D-galactopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: p-methylphenylsulfonyl 2,3,4,6-tetra-O-acetyl-1-deoxy-β-D-galactopyranoside(100762-19-4)
• EPA Substance Registry System: p-methylphenylsulfonyl 2,3,4,6-tetra-O-acetyl-1-deoxy-β-D-galactopyranoside(100762-19-4)

Safety Data

• Hazardous Substances Data: 100762-19-4(Hazardous Substances Data)

Upstream product

• 4163-60-4 β-D-galactose peracetate 
• 28244-94-2 4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside 

Relevant articles and documents

Selective Oxidation of Glycosyl Sulfides to Sulfoxides Using Magnesium Monoperoxyphthalate and Microwave Irradiation

A protocol that uses moist magnesium monoperoxyphthalate (MMPP) as an oxidant under microwave irradiation rapidly yields a variety of glycosyl sulfoxides from corresponding sulfides in high yields with high selectivity.

Urea–hydrogen peroxide prompted the selective and controlled oxidation of thioglycosides into sulfoxides and sulfones

A practical method for the selective and controlled oxidation of thioglycosides to corresponding glycosyl sulfoxides and sulfones is reported using urea–hydrogen peroxide (UHP). A wide range of glycosyl sulfoxides are selectively achieved using 1.5 equiv of UHP at 60 °C while corresponding sulfones are achieved using 2.5 equiv of UHP at 80 °C in acetic acid. Remarkably, oxidation susceptible olefin functional groups were found to be stable during the oxidation of sulfide.